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Er3+/Eu3+及Yb3+/Er3+/Eu3+共掺杂硼硅酸盐玻璃的上转换发光分析
Up-conversion Emission Analysis of Er3+/Eu3+ Co-doped and Yb3+ /Er3+ /Eu3+ Co-doped Borosilicate Glasses
- 发光学报 2010年31卷第6期 页码：816-820
- 作者机构：
1. 大连理工大学 物理与光电工程学院,辽宁 大连,116024
2. 辽宁师范大学 物理与电子技术学院,辽宁 大连,116029
- 作者简介：
- 基金信息：国家自然科学基金(10804015)();辽宁省教育厅项目(2009A417)资助项目()
DOI：
中图分类号： O482.31收稿日期：2010-01-25，
修回日期：2010-06-24，
网络出版日期：2010-11-22，
纸质出版日期：2010-11-22
- 稿件说明：
移动端阅览
殷海涛, 李成仁, 程宇琪, 李淑凤, 张丽. Er<sup>3+</sup>/Eu<sup>3+</sup>及Yb<sup>3+</sup>/Er<sup>3+</sup>/Eu<sup>3+</sup>共掺杂硼硅酸盐玻璃的上转换发光分析[J]. 发光学报, 2010,31(6): 816-820
YIN Hai-tao, LI Cheng-ren, CHENG Yu-qi, LI Shu-feng, ZHANG Li. Up-conversion Emission Analysis of Er<sup>3+</sup>/Eu<sup>3+</sup> Co-doped and Yb<sup>3+</sup> /Er<sup>3+</sup> /Eu<sup>3+</sup> Co-doped Borosilicate Glasses[J]. Chinese Journal of Luminescence, 2010,31(6): 816-820
殷海涛, 李成仁, 程宇琪, 李淑凤, 张丽. Er<sup>3+</sup>/Eu<sup>3+</sup>及Yb<sup>3+</sup>/Er<sup>3+</sup>/Eu<sup>3+</sup>共掺杂硼硅酸盐玻璃的上转换发光分析[J]. 发光学报, 2010,31(6): 816-820 DOI：
YIN Hai-tao, LI Cheng-ren, CHENG Yu-qi, LI Shu-feng, ZHANG Li. Up-conversion Emission Analysis of Er<sup>3+</sup>/Eu<sup>3+</sup> Co-doped and Yb<sup>3+</sup> /Er<sup>3+</sup> /Eu<sup>3+</sup> Co-doped Borosilicate Glasses[J]. Chinese Journal of Luminescence, 2010,31(6): 816-820 DOI：
摘要
采用高温固相烧结法制备了Er
3+
/Eu
3+
共掺杂和Yb
3+
/Er
3+
/Eu
3+
共掺杂系列硼硅酸盐玻璃样品。在978nm半导体激光器抽运下
测量了样品的光致发光谱
分析了上转换机制。结果表明:随着Er
3+
浓度的增加
Eu
3+
的595nm光谱强度增强;Eu
3+
的692nm光谱强度随Yb
3+
浓度增加而增强
并明显强于595nm光谱。Er
3+
/Eu
3+
、Yb
3+
/Eu
3+
之间的能量传递和合作上转换等机制导致Eu
3+
离子上转换发射。
Abstract
A series of Er
3+
/Eu
3+
co-doped
Yb
3+
/Er
3+
/Eu
3+
co-doped borosilicate glasses have been prepared by high-temperature solid-phase melting. Under 978 nm semiconductor laser excitation
the up-conversion emission spectra of the samples were measured
and up-conversion mechanism was analyzed. The emission intensities of Eu
3+
ions at 595 nm and 692 nm were enhanced with increasing concentration of Er
3+
Yb
3+
respectively. And emission intensity at 692 nm is stronger than that at 595 nm. The cooperation up-conversion and the energy transfer between Yb
3+
and Eu
3+
Er
3+
and Eu
3+
lead to a strong up-conversion emission of trivalent europium ions.
关键词
Keywords
references
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