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福建师范大学化学与材料学院高分子研究所,福建 福州,350007
收稿日期:2009-05-26,
修回日期:1900-01-02,
网络出版日期:2010-06-30,
纸质出版日期:2010-06-30
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林炳丽, 章文贡, 欧阳锐, 等. 含铕类水滑石/聚苯胺导电性复合材料的荧光[J]. 发光学报, 2010,31(3):427-432.
LIN Bing-li, ZHANG Wen-gong, OUYANG Rui, et al. Fluorescence of Conductive Composite Material with Eu-HTLc/PAN-CSA[J]. Chinese journal of luminescence, 2010, 31(3): 427-432.
采用超声法将定量的荧光性含铕类水滑石(Eu-HTLc)掺混到导电性聚苯胺(PAN-CSA)中
获得一类新型的含铕类水滑石/聚苯胺导电性荧光复合材料(Eu-HTLc/PAN-CSA)。采用电导率测试、荧光光谱、红外光谱、X射线衍射和热分析等手段对其进行表征。研究结果表明:该复合材料的电导率
σ
=7.97×10
-3
(S/cm);在紫外光下该复合材料可发出红色荧光(613 nm)
其荧光寿命为441.32 μs;热分析结果显示
该复合材料比PAN-CSA具有更高热稳定性
有望作为一类新型荧光材料而获得应用。
A fluorescent and conductive composite material was formed by doping Eu-containing hydrotalcite-like compound in the polyaniline.The structure and properties have been characterized with electrical conductivity methods
fluorescence spectrum
FT-IR techniques
X-ray diffraction (XRD) and thermogravimetric analysis(TG).The results showed that the composite material was a semiconductor material which had good fluorescence propertics.Otherwise
the composite material had better thermal stability than the relevant PAN-CSA.The composite material may become a promising candidate for new fluorescent materials.
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