苯氧乙酸、邻菲啰啉铽-钇配合物的合成、表征及荧光性能

王 艳; 赵永亮; 李欢欢; 魏晓燕; 马瑞军; 杜 燕

doi:null

您当前的位置：

首页 >

文章列表页 >

苯氧乙酸、邻菲啰啉铽-钇配合物的合成、表征及荧光性能

论文 | 更新时间：2020-08-12

- 苯氧乙酸、邻菲啰啉铽-钇配合物的合成、表征及荧光性能
- Synthesis, Characterization and Fluorescence Properties of Y³⁺ -Doped Terbium Complexes with Phenoxyacetic Acid and 1,10-Phenanthroline
- 发光学报 2010年31卷第3期页码：405-410
- 作者机构：
  
  内蒙古大学化学化工学院,内蒙古呼和浩特,010021
- 作者简介：
- 基金信息：
- DOI：
  中图分类号： O641.4;O482.31
- 收稿日期：2009-09-10，
  
  修回日期：1900-01-02，
  
  网络出版日期：2010-06-30，
  
  纸质出版日期：2010-06-30
- 稿件说明：
移动端阅览
王艳, 赵永亮, 李欢欢, 等. 苯氧乙酸、邻菲啰啉铽-钇配合物的合成、表征及荧光性能[J]. 发光学报, 2010,31(3):405-410.

WANG Yan, ZHAO Yong-liang, LI Huan-huan, et al. Synthesis, Characterization and Fluorescence Properties of Y³⁺ -Doped Terbium Complexes with Phenoxyacetic Acid and 1,10-Phenanthroline[J]. Chinese journal of luminescence, 2010, 31(3): 405-410.
王艳, 赵永亮, 李欢欢, 等. 苯氧乙酸、邻菲啰啉铽-钇配合物的合成、表征及荧光性能[J]. 发光学报, 2010,31(3):405-410. DOI：

WANG Yan, ZHAO Yong-liang, LI Huan-huan, et al. Synthesis, Characterization and Fluorescence Properties of Y³⁺ -Doped Terbium Complexes with Phenoxyacetic Acid and 1,10-Phenanthroline[J]. Chinese journal of luminescence, 2010, 31(3): 405-410. DOI：

摘要

以苯氧乙酸和邻菲啰啉为配体

不同比例铽钇为中心

在无水乙醇中合成了一系列铽掺钇配合物。元素分析和稀土络合滴定推测配合物的组成为Tb

1-x

(POA)

phen·1/2H

O (POA

OCH

COO

x=1.0

0.9

0.8

0.7

0.6

0.5

0.4

0.3

0.2

0.1)。红外光谱测试表明

苯氧乙酸的羧基氧及苯氧基氧与稀土离子配位。邻菲啰啉的两个氮原子也与稀土离子配位;热分析表明:该系列配合物在274 ℃附近失去配位水

温度高于576 ℃发生氧化分解。荧光光谱测试结果表明:该系列配合物都可发出较强的特征荧光

在一定比例范围内

钇可以增强铽的发光

组成为配合物Tb

0.7

0.3

(POA)

phen·1/2H

O荧光最强;荧光寿命与荧光强度变化一致。

Abstract

A series of Y

-doped terbium complexes with phenoxyacetic acid and 1

10-phenanthroline were synthesized in anhydrous alcohol. Elemental analysis and rare earth complexometic titration showed that the composition of the complexes are Tb

1-x

(POA)

phen·1/2H

O(POA=C

OCH

COO

x=1.0

0.9

0.8

0.7

0.6

0.5

0.4

0.3

0.2 and 0.1). The IR absorption spectra indicated that the rare earth ions are bounded with the oxygen atoms of phenoxyacetic acid and phenoxy

and with two nitrogen atoms of 1

10-phenanthroline. Thermogram and thermogravimetric analysis indicated that the complexes release coordinated water at about 274 ℃ and they are stable below 576 ℃. Fluorescent spectra showed that the fluorescence intensity of the series Tb

complexes can be greatly enhanced if some of terbium ions in the complexes are substituted by Y

. The fluorescence lifetime of the complexes exhibits the similar feature to the fluorescence intensities.

关键词

Keywords

references

. Silva F R G, Menezes J F S, Rocha G B, et al. Emission quantum yield of europium (Ⅲ) mixed complexes with thenoyltrifluoroacetonate and some aromatic ligands [J]. J. Alloys and Compounds, 2000, 303-304 :364-370.

. Hnatejko Z, Embanowski M. Complexation, luminescence and energy transfer of Ln(Ⅲ) ions with phenylphosphonic acid [J]. J. Alloys and Compounds, 2004, 380 (1-2):181-185.

. Wang Xigui, Wu Hongying, Yao Guangqing, et al. Study on the transition of green yellow fluorescence of ternary complexes of Tb-Benzoic acid-1,10-phenanthroline [J]. Spectroscopy and Spectral Analysis (光谱学与光谱分析), 2004, 24 (6):708-712 (in Chinese).

. Gear W J. The use of conductivity measurements in organic solvents for the characterization of coordination compounds [J]. Coord. Chem. Rew., 1971, 7 (1):81-122.

. Liu Yunlong, Wang Wenjun, Gao Xuexi, et al. Study on fluorescence properties of sandwich bisphthalocyanine terbium [J]. Chin. J. Lumin. (发光学报), 2008, 29 (1):67-70 (in Chinese).

. Wang Lianmeng, Zhao Yongling, Zhou Yongsheng, et al. Synthesis, characterization and photoluminescence properties of (EuxRE1-x)(FTFA)e phen complexes [J]. Chin. J. Lumin. (发光学报), 2008, 29 (6):1086-1090 (in Chinese).

. Tan Hui, Wnag Liying, Zhou Yue, et al. Synthesis and optical properties of complexes of terbium with aromatic compounds and succinic acid [J]. Chin. J. Lumin. (发光学报), 2008, 30 (1):101-107 (in Chinese).

. Latva M, Takalo H, Simberg K, et al. Enhanced Eu(Ⅲ) ion luminescence and efficient energy transfer between lanthanide chelates within the polymeric structure in aqueous solutions [J]. J. Chem. Soc. Perkin Trans. (Ⅱ), 1995, (5):995-999.

. Wang J F, Wang R Y, Yang J, et al. First oxadiazole-functionalized terbium(Ⅲ)β-diketonate for organic electroluminescence [J]. J. Am. Chem. Soc., 2001, 123 (25):6179-6180.

. Pettinari C, Marchetti F, Pettinari R, et al. Synthesis, structure and luminescence properties of new rare earth metal complexes with 1-phenyl-3-methyl-4-acylpyrazol-5-ones [J]. J. Chem. Soc., Dalton Trans., 2002, 2 (7):1409-1415.

. Zhao Y L, Zhao F Y, Xue Z, et al. Infrared spectra and luminescent properties of p-tert-butycalix

. arene-DMF complexes of rare earth nitrates [J]. Chin. J. Lumin.(发光学报), 2006, 27 (3):358-361 (in Chinese).

. Blasse G. Luminescence of rare earth ions at the end of the century [J]. J. Alloys Comp., 1993, 192 (1-2):17-21.

. Toylar M D, Carter C D, Wynter C I. The Infra-red spectra and structure of the rare-earth benzoates [J]. J. Inorg. Nucl. Chem., 1968, 30 (6):1503-15-11.

. Zhao Yongliang, Zhao Fengying. Synthesis and luminescence of complexes Eu<em>xY1-x(phen)L3 [J]. J. Rare Earths, 2002, 20 (5):427-429.

. Zhang Lixia, Liang Lifang, Mo Yijuan, et al. Characterization of rare earth complexes with phenoxyacetic acid and their effect on plant Pb, Cd pollution [J]. Chin. Rare Earths (稀土), 2006, 27 (2):270-274 (in Chinese).

. Li Y, Zhao Y L. Intramolecular energy transfer and Co-luminescence effect in rare earth ions (La, Y, Gd and Tb) doped with Eu3+ β-diketone complexes [J]. Journal of Fluorescence, 2009, 19 (4):641-647.

浏览量

下载量

CSCD

文章被引用时，请邮件提醒。

提交

工具集

关联资源

均苯三甲酸铕掺杂配合物的合成及其荧光性能

RE(POA)₃phen配合物的合成、表征及荧光性能

苯甲酸含氮杂环镝配合物的合成、表征及发光性质

含稀土铕(Ⅲ)配合物光学树脂的制备及光学性能的研究