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大连理工大学 物理与光电工程学院,辽宁 大连,116024
收稿日期:2009-11-25,
修回日期:1900-01-02,
网络出版日期:2010-04-30,
纸质出版日期:2010-04-30
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孙开通, 胡礼中, 于东麒, 等. PLD方法制备的ZnO纳米柱结构及光学特性[J]. 发光学报, 2010,31(2):261-264.
SUN Kai-tong, HU Li-zhong, YU Dong-qi, et al. Structural and Optical Properties of ZnO Nanorods Synthsized by PLD Method[J]. Chinese journal of luminescence, 2010, 31(2): 261-264.
采用无催化脉冲激光沉积(PLD)方法,在 InP(100)衬底上生长纳米ZnO柱状结构。采用扫描电子显微镜(SEM)、X射线衍射(XRD)以及光致发光(PL)谱等表征手段对ZnO纳米柱的形貌、晶体结构和光学特性进行了观察。SEM图像观察到ZnO纳米柱状结构具有一定的取向性;XRD测试在 2θ=34.10°处观测到强的ZnO(002)衍射峰,证实ZnO纳米柱具有较好的c轴择优取向;室温PL谱在379 nm处观察到了强的自由激子发射峰(半峰全宽为19 nm),未探测到深能级跃迁发射峰,表明生长的纳米ZnO结构具有很高的光学质量。
One-dimensional (1D) semiconducting nanomaterials have attracted considerable interest for their potential applications in optoelectronic and microelectronic devices. Among thoses 1D semiconducting nanomaterials
ZnO is a wide band gap semiconductor and one of the most functional materials. On account of its many interesting properties
such as superior emission
chemical and thermal stability
transparency
biocompatibility
and wide electrical conductivity range
ZnO has a variety of applications in an emerging area of nanotechnology. Moreover
as a very important one of ZnO nanostructure groups
ZnO nanorods(NRs) have wide applications in nanoelectronics including nanobased light-emitting diodes (LEDs)
field effect transistors (FETs)
ultraviolet (UV) lasers
and nanogenerators. Until now
there are numerous experimental methods to prepare ZnO NRs involving molecular beam epitaxy (MBE)
sputtering
electrochemical deposition
vapor phase transport (VPT)
chemical vapor deposition (CVD)
and thermal evaporation. However
most of these attempts need some kind of metals to act as a catalyzer. Aurum
zinc
argentine
and aluminium are often used in these methods
which make the prepared ZnO NRs impure. In the cases the metallic impurities have awful influence on the electrical and optical properties of ZnO NRs
an advanced and catalyst-free ZnO growth method needs to be exploited.In this paper
ZnO NRs were successfully synthesized on indium phosphide (InP) (100) substrates by using pulsed laser deposition (PLD) method with catalyst-free. The morphology
crystal structural and optical properties were characterized with scanning electron microscopy (SEM)
X-ray diffraction (XRD) and photoluminescence (PL) analytic approaches
respectively. SEM pattern showed the ZnO nanorods were well-oriented. From the XRD scan results
a strong peak was observed at 34.10° attributed to the ZnO (002) face
indicating that the growth direction is well-oriented along c axis. A typical PL spectrum was measured at room temperature
showing a strong free-excition emission at about 379 nm
with full width at half maximum (FWHM) value of 19 nm
no deep level emission was detected
indicating that the ZnO nanorods produced in this experiment are of high optical quality.
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