Y0.795-xGdxYb0.2Tm0.005F3纳米晶合成及 Tm3+和Gd3+的上转换发光

曹春燕; 秦伟平; 张继森; 荀显超

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Y_0.795-xGd_xYb_0.2Tm_0.005F₃纳米晶合成及 Tm³⁺和Gd³⁺的上转换发光

论文 | 更新时间：2020-08-12

- Y_0.795-xGd_xYb_0.2Tm_0.005F₃纳米晶合成及 Tm³⁺和Gd³⁺的上转换发光
- Synthesis and Up-conversion Emission Properties of Y_0.795-xGd_xYb_0.2Tm_0.005F₃ Nanocrystals
- 发光学报 2009年30卷第6期页码：738-743
- 作者机构：
  
  1. 中国科学院长春光学精密机械与物理研究所激发态物理重点实验室,吉林长春,130033
  2. 井冈山大学数理学院,江西吉安,343009
  3. 吉林大学电子科学与工程学院集成光电子国家重点实验室,吉林长春,130012
  4. 空军航空大学,吉林长春,130022
- 作者简介：
- 基金信息：
- DOI：
  中图分类号： O482.31
- 收稿日期：2009-02-25，
  
  修回日期：1900-01-02，
  
  网络出版日期：2009-12-30，
  
  纸质出版日期：2009-12-30
- 稿件说明：
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曹春燕, 秦伟平, 张继森, 等. Y_0.795-xGd_xYb_0.2Tm_0.005F₃纳米晶合成及 Tm³⁺和Gd³⁺的上转换发光[J]. 发光学报, 2009,30(6):738-743.

CAO Chun-yan, QIN Wei-ping, ZHANG Ji-sen, et al. Synthesis and Up-conversion Emission Properties of Y_0.795-xGd_xYb_0.2Tm_0.005F₃ Nanocrystals[J]. Chinese journal of luminescence, 2009, 30(6): 738-743.
曹春燕, 秦伟平, 张继森, 等. Y_0.795-xGd_xYb_0.2Tm_0.005F₃纳米晶合成及 Tm³⁺和Gd³⁺的上转换发光[J]. 发光学报, 2009,30(6):738-743. DOI：

CAO Chun-yan, QIN Wei-ping, ZHANG Ji-sen, et al. Synthesis and Up-conversion Emission Properties of Y_0.795-xGd_xYb_0.2Tm_0.005F₃ Nanocrystals[J]. Chinese journal of luminescence, 2009, 30(6): 738-743. DOI：

摘要

利用水热法合成了氟化物Y

0.795-x

0.2

0.005

(x=0.0

0.1

0.2

0.5

0.8)纳米晶。研究了退火后系列样品的上转换发光性质以及激发态辐射跃迁寿命。在980 nm激发下

0.795-x

0.2

0.005

纳米微晶样品中观察到了Tm

的蓝光上转换发射及紫色、紫外发射增强现象

同时还观察到Gd

的

9/2

、

5/2

及

7/2

到基态

7/2

的发射。实验结果表明:样品半个波长量级的颗粒尺寸是Tm

紫外上转换增强以及Tm

到Gd

发生有效能量传递的重要因素。

Abstract

0.795-x

0.2

0.005

nanocrystals were synthesized through a hydrothermal method. After annealing in the air conditions

the upconversion (UC) emission properties under a 980 nm continuous wave semiconductor laser diode excitation were studied. The experimental results suggested that the violet and ultraviolet (UV) UC emission enhancement were observed in Y

0.795-x

0.2

0.005

nanocrystals

as well as the UC emissions from

9/2

5/2

and

7/2

states to the ground state

7/2

of Gd

were shown

too. The luminescent kinetic analysis implied that

under 980 nm excitation

can transfer energy to populate the

level of Tm

make UV

violet

and blue UC emissions obtained

further

the

multiplets of Gd

were populated through the energy transfer process

→

(Tm

7/2

→

(Gd

). At the same time

the energy transfer processes occurred between Gd

and Yb

or Tm

based on the energy matching conditions

leading to the above mentioned UV UC emissions of Gd

关键词

Keywords

references

. Auzel F. Upconversion and anti-Stokes processes with f and d ions in solids [J]. Chem. Rev., 2004, 104 (1):139-173.

. Thomas G E. Future trends in optical recordings [J]. Philips Tech. Rev., 1988, 44 :51-57.

. Miyajima T, Tojyo T, Asano T, et al. GaN-based blue laser diodes [J]. J. Phys. Conden. Matter., 2001, 13 (32):7099-7114.

. Johnson L F, Guggenheim H J. Infrared-pumped visible laser [J]. Appl. Phys. Lett., 1971, 19 (2):44-46.

. Joubert M F. Photon avalanche upconversion in rare earth laser materials [J]. Opt. Mat., 1999, 11 (2-3):181-203.

. Heumann E, Bar S, Kretschmann, et al. Diode-pumped CW green upconversion lasing of Er3+ ∶ LiLuF4 using multipass pumping [J]. Opt. Lett., 2002, 38 (25):1699-1701.

. Paschotta R, Moore N, Clarkson W A, et al. 230 mW of blue light from a thulium-doped upconversion fiber laser [J]. IEEE J. Selected Topics in Quantum Elect., 1997, 3 (4):1100-1102.

. Dieke G H. Spectra and Energy Levels of Rare Earth Ions in Crystals [M]. New York: Interscience Academic, 1968.

. Carnall W T, Goodman G L, Rajnak K, et al. A systematic analysis of the spectra of the lanthanides doped into single crystal LaF3 [J]. J. Chem. Phys., 1989, 90 (7):3443-3457.

. Kumar A, Rai D K, Rai S B. Luminescence of Gd3+ ions doped in oxyfluoroborate glass [J]. Solid State Commun., 2001, 117 (6):387-392.

. Kondo H, Hirai T, Hashimoto S. Energy migration and relaxation through Gd3+ sublattice in NaGdF4 [J]. J. Lumin., 2003, 102-103 :727-732.

. Gharavi A R, McPherson G L. Ultraviolet emissions from Gd3+ ions excited by energy transfer from pairs of photoexcited Er3+ ions: upconversion luminescence from CsMgCl3 crystals doped with Gd3+ and Er3+[J]. J. Opt. Soc. Am. B, 1994, 11 (5):913-918.

. Cao C Y, Qin W P, Zhang J S, et al. Ultraviolet upconversion emissions of Gd3+ [J]. Opt. Lett., 2008, 33 (8):857-859.

. Qin W P, Cao C Y, Zhang J S, et al. Ultraviolet upconversion fluorescence from 6DJ of Gd3+ induced by 980 nm excitation [J]. Opt. Lett., 2008, 33 (8):2167-2169.

. Cao C Y, Qin W P, Zhang J S, et al. Up-conversion emission properties of Tm3+/Er3+/Yb3+ tri-doped YF3 powders depending on excitation power,annealed temperature and Tm3+ concentration [J]. Chin. J. Lumin. (发光学报), 2007, 28 (5):705-711 (in Chinese).

. Glinka Y D, Everitt H O, Lee D S, et al. Effect of Tm3+-induced defects on the photoexcitation energy relaxation in Tm-doped AlxGa1-xN [J]. Phys. Rev. B, 2009, 79 (11):113202-1-4.

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