高脉冲功率能量PLD法制备MgZnO薄膜中的沉积机理

汪壮兵; 李 祥; 于永强; 梁 齐; 揭建胜; 许小亮

doi:null

您当前的位置：

首页 >

文章列表页 >

高脉冲功率能量PLD法制备MgZnO薄膜中的沉积机理

论文 | 更新时间：2020-08-12

- 高脉冲功率能量PLD法制备MgZnO薄膜中的沉积机理
- The Deposition Mechanism of MgZnO Films by PLD with High Pulse Energy
- 发光学报 2009年30卷第3期页码：344-350
- 作者机构：
  
  1. 中国科学技术大学物理系, 安徽合肥 230026
  2. 合肥工业大学应用物理系,安徽合肥,230009
- 作者简介：
- 基金信息：
- DOI：
  中图分类号： O482.31
- 收稿日期：2009-02-13，
  
  修回日期：1900-01-02，
  
  网络出版日期：2009-06-30，
  
  纸质出版日期：2009-06-30
- 稿件说明：
移动端阅览
汪壮兵, 李祥, 于永强, 等. 高脉冲功率能量PLD法制备MgZnO薄膜中的沉积机理[J]. 发光学报, 2009,30(3):344-350.

WANG Zhuang-bing, LI Xiang, YU Yong-qiang, et al. The Deposition Mechanism of MgZnO Films by PLD with High Pulse Energy[J]. Chinese journal of luminescence, 2009, 30(3): 344-350.
汪壮兵, 李祥, 于永强, 等. 高脉冲功率能量PLD法制备MgZnO薄膜中的沉积机理[J]. 发光学报, 2009,30(3):344-350. DOI：

WANG Zhuang-bing, LI Xiang, YU Yong-qiang, et al. The Deposition Mechanism of MgZnO Films by PLD with High Pulse Energy[J]. Chinese journal of luminescence, 2009, 30(3): 344-350. DOI：

摘要

用PLD法成功制备了一系列高质量的MgZnO薄膜。实验中发现高脉冲能量沉积薄膜的结构和发光特性随基片温度的变化规律与低脉冲能量下的结果不一样:基片在室温时高脉冲能量制备薄膜的XRD峰的半峰全宽比高基片温度时的结果相对更小;AFM显示其颗粒变大

柱状生长突出;PL谱紫峰与绿峰强度比最大

结晶质量反而提高。另一方面

与低脉冲能量时相反

增大氧气压强后高脉冲能量沉积的薄膜XRD半峰全宽变窄。结合实验现象和表征

合理解释了高脉冲能量沉积的机理。室温制备高质量MgZnO薄膜的PLD沉积机理对于以后在柔性衬底上沉积薄膜的研究有重要的参考价值。

Abstract

A series of high quality MgZnO films are successfully prepared by pulsed laser deposition (PLD) on silicon substrate.It was discovered that with high laser pulse energy deposition the substrate temperature dependence of the structure and luminescence characteristic of the films is not consistent with that under low laser pulse energy. Compared with higher substrate temperature

it is abnormal that the film deposited at room temperature with high laser pulse energy exhibits narrower full width at half maximum (FWHM) of X-ray diffraction (XRD)

bigger grain size and roughness of root mean square (RMS) by atomic force microscopy (AFM). Moreover

the photoluminescence (PL) spectra show that the intensity of ultraviolet peak was enhanced remarkably and the ratio of ultraviolet peak to green peak is the largest when the film was deposited at room temperature. It can be concluded that the crystal quality of the film deposited with high laser pulse energy at room temperature is better than that of the film deposited at higher temperature. The growth of MgZnO film consists of plane and column direction

which is the preferred orientation because of lowest surface energy. There is strike of plasma plume against the film during high laser pulse energy deposition

which would result in more particles deviation from film with the increase of substrate temperature. However

even at room temperature the particles directly deposited on substrate have enough residual energy due to high laser pulse energy to form high quality film. The FWHM of XRD of the film deposited with high laser pulse energy decreases as the oxygen pressure increases

which is a indirect proof that the enhanced oxygen pressure would weaken the strike of plasma plume against the film. Our work would be of great benefit to the research of growth high quality MgZnO films on flexible substrate at low temperature.

关键词

Keywords

references

. Dong Xin, Zhao Wang, Zhang Baolin, et al. Study on optical properties of p-type MgZnO fabricated by MOCVD [J].Chin. J. Lumin. (发光学报), 2008, 29 (1):129-132 (in Chinese).

. Dong Lipu, Liu Yuxue, Xu changshan, et al. High quality MgxZn1-xO films fabricated by electron beam evaporation combined with heat treatment [J]. Chin. J. Lumin. (发光学报), 2008, 29 (2):313-317 (in Chinese).

. Liu Ying, Yang Shenghong, Zhang Yueli, et al. Structural and optical properties of MgxZn1-xO thin films prepared by sol-gel method [J]. Chin. J. Lumin. (发光学报), 2008, 29 (4):718-722 (in Chinese).

. Jiang Dayong, Zhang Jiying, Shan Chongxin, et al. Solar-brind photodetector based on MgZnO thin films [J]. Chin. J. Lumin. (发光学报), 2008, 29 (4):743-746 (in Chinese).

. Liu M, Wei X Q, Zhang Z G, et al. Effect of temperature on pulsed laser deposition of ZnO films [J]. Appl. Surf. Sci.,2006, 252 (12):4321-4326.

. Fan X M, Lian J S, Guo Z X, et al. Microstructure and photoluminescence properties of ZnO thin films grown by PLD on Si(111) substrates [J]. Appl. Surf. Sci., 2005, 239 (2):176-181.

. Zou Jun, Zhou Shengming, Xia Changtai, et al. Structure, optical and electrical properties of ZnO films grown on c-plane sapphire and (100) γ-LiAlO2 by pulse laser deposition [J]. J. Crystal Growth, 2005, 280 (1-2):185-190.

. Wang Zhaoyang, Hu Lizhong, Zhao Jie, et al. Effect of the variation of temperature on the structure and optical properties of ZnO thin films prepared on Si(111) substrate using PLD [J]. Vacuum, 2005, 78 (1):53-57.

. Bian Jiming, Du Guotong, Hu Lizhong, et al. Growth and photoluminescence characteristics of high quality ZnO films by pulsed laser deposition (PLD) method [J]. Chin. J. Lumin.(发光学报), 2006, 27 (6):958-962 (in Chinese).

. Zhu B L, Zhao X Z, Su F H, et al. Structural and optical properties of ZnO thin films on glass substrate grown by laser-ablating Zn target in oxygen atmosphere [J]. Phys. B, 2007, 396 (1-2):95-101.

. Dong Lin, Ma Ying, Li hao, et al. Preparation of Cu/Cu2O thin films on flexible ITO substrates via electrochemical deposition [J]. Chin. J. Lumin.(发光学报), 2007, 28 (5):798-801 (in Chinese).

. Choopum S, Vispute R D, Zoch W, Oxygen pressure-tuned epitaxy and optoelectronic properties of laser-deposited ZnO films on sapphire [J]. Appl. Phys. Lett., 1999, 75 (25):3947-3949.

. Xu Xiaoliang, Guo Changxin, Qi Zemin, et al. Annealing effect for surface morphology and luminescence of ZnO film on silicon [J]. Chem. Phys. Lett., 2002, 364 (1-2):57-63.

. Fan X M, Lian J S, Jiang Qing, et al. Effect of oxygen pressure on the photoluminescence properties of ZnO thin films by PLD [J]. J. Mater. Sci., 2007, 42 (8):2678-2683.

. Zhang Lide. Nano-material and Nanostructure [M]. Beijing: Academic Press, 2001, 148.

浏览量

163

下载量

CSCD

文章被引用时，请邮件提醒。

提交

工具集

关联资源

原子力显微镜在PLD法制备ZnO薄膜表征中的应用

氮掺杂氧化锌薄膜的光电特性

常压MOCVD生长Ga₂O₃薄膜及其分析

高质量立方相ZnMgO的制备与紫外受激发射特性研究

Mn掺杂对ZnO薄膜结构及发光性能的影响