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北京交通大学光电子研究所 发光与光信息技术教育部重点实验室 北京,100044
收稿日期:2008-10-25,
修回日期:1900-01-02,
网络出版日期:2009-02-20,
纸质出版日期:2009-02-20
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滕 枫, 李扬舟. Poly ∶ DCJTB 为功能层LEC器件的能量传递[J]. 发光学报, 2009,30(1):59-62.
TENG Feng, LI Yang-zhou. Energy Transfer in Co-polymer Poly Doped DCJTB in LEC Device[J]. Chinese journal of luminescence, 2009, 30(1): 59-62.
在有机发光器件中
掺杂染料分子是改变发光颜色
提高发光性能的有利手段。在掺杂体系中
主体材料向掺杂剂的能量传递是主要的激发态弛豫过程。在LEC器件中
利用掺杂手段改变发光颜色的方法报道很少。研究了以发射绿光(峰值550 nm)的共聚物Poly 中掺杂DCJTB作为功能层的LEC器件的发光特性。器件的结构为ITO/Poly ∶ DCJTB+PEO+LiCF
3
SO
3
/Al。共聚物的光致发光光谱几乎覆盖了整个DCJTB吸收光谱的范围
满足能量传递的要求。通过光致发光与电致发光光谱的研究
发现掺杂后的薄膜不论是光致发光还是电致发光
都以DCJTB的发射为主
说明二者之间的确存在能量传递。
It is a general method to vary emission color by doping dyes in OLED devices. The energy transfer from host to dyes is important process in blend system in OLED devices. In this paper
the spectra of the active layer based on co-polymer poly doped with DCJTB were studied in LEC devices. The structure of the device is ITO/poly∶DCJTB +PEO +LiCF
3
SO
3
/Al.The photoluminescence (PL) spectrum of the co-polymer (peak at 550 nm) is almost cover the absorption spectrum of DCJTB completely
it is necessary for energy transfer from co-polymer to DCJTB. When the blend film was exited by the absorption peak of the co-polymer (450 nm)
where there is no absorption of DCJTB
the PL spectra exhibit the emission properties of DCJTB mainly
and the electroluminescence (EL) spectra of the LEC device show similar properties as PL spectra. This result showed that the energy transfer between the co-polymer and DCJTB plays important roles in the active layer of LEC device.
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