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浙江大学硅材料国家重点实验室, 材料科学与工程系, 浙江, 杭州, 310027
收稿日期:2007-12-16,
修回日期:2008-01-24,
纸质出版日期:2008-07-20
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胡翔, 李东升, 程培红, 袁志钟, 杨德仁. 表面等离激元对氮化硅薄膜中Tb<sup>3+</sup>离子荧光寿命的影响[J]. 发光学报, 2008,29(4): 684-688
HU Xiang, LI Dong-sheng, CHENG Pei-hong, YUAN Zhi-zhong, YANG De-ren . Effects of Surface Plasmon on the Photoluminescence Emission Decay Time of Tb<sup>3+</sup> Doped SiN<sub>x</sub> Films[J]. Chinese Journal of Luminescence, 2008,29(4): 684-688
胡翔, 李东升, 程培红, 袁志钟, 杨德仁. 表面等离激元对氮化硅薄膜中Tb<sup>3+</sup>离子荧光寿命的影响[J]. 发光学报, 2008,29(4): 684-688 DOI:
HU Xiang, LI Dong-sheng, CHENG Pei-hong, YUAN Zhi-zhong, YANG De-ren . Effects of Surface Plasmon on the Photoluminescence Emission Decay Time of Tb<sup>3+</sup> Doped SiN<sub>x</sub> Films[J]. Chinese Journal of Luminescence, 2008,29(4): 684-688 DOI:
利用等离子增强化学气相沉积和离子注入方法
制备了铽掺杂的氮化硅薄膜
然后利用磁控溅射和热处理工艺在薄膜上沉积了不同颗粒尺寸的银薄膜来研究表面等离激元共振对铽离子荧光寿命的影响.实验结果表明氮化硅中Tb
3+
离子的光致荧光最强峰在547 nm
而银薄膜的存在会明显降低稀土离子Tb
3+
的荧光寿命
其寿命的改变是由于银薄膜的表面等离激元改变了电磁场的分布
从而影响了系统的局域光模密度(PMD)
理论计算的结果也验证了这一点.
The motivation for developing silicon-based light emitters is the requirement of tiny light sources in the visible regions
which can be directly integrated into silicon chips for the analysis of different biological substances
for silicon optical couplers
and high-resolution low-cost micro displays.It is believed that the development of integrate circuit will open a door for the continuous increasing of silicon-based light emitters predicted by Moore's law.Many efforts
such as bulk silicon
Si nanocrystals
and rare earth(RE)coupled Si nanocrystals have been extensively studied.Weighing the studies mentioned above
rare RE-doped silicon light emitter
which has intense light emission even at room temperature
is a better candidate.In this report
the photoluminescence of Tb implanted SiN
x
films grown by plasma-enhanced chemical vapor deposition(PECVD)was investigated.And the effects of surface plasmon on the photoluminescence emission decay time of Tb
3+
doped SiN
x
films with different sized of Ag islands films were investigated.The photoluminescence(PL)and time resolved photoluminescence(TRPL)at room temperature show that the PL of SiN
x
:Tb
3+
film has the highest intensity at 547 nm with corresponding emission decay time 708 ms.After sputtering silver films
the TRPL of Tb
3+
ions shows the decrease of the emission decay time.An increase of emission decay time was observed due to the increased size of Ag islands after rapid thermal processing(RTP).We find good agreement between our experimental results and those predicted by a classical theory
which assumes the emitter to be a damped oscillating electric dipole.Therefore
it allows one to be confident that the silver islands do altered the emission decay time which correspondingly improve the internal quantum efficiency of the SiN
x
:Tb
3+
.
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