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台湾中兴大学, 材料科学及工程学系,台湾 台中
收稿日期:2007-10-25,
修回日期:2007-12-15,
纸质出版日期:2008-05-20
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吴嘉城, 林伯融, 陈采宁, 游亭恩, 武东星. 用于氮化镓发光二极管窗口层的铝掺杂氧化锌的生长[J]. 发光学报, 2008,29(3): 508-512
WU Chia-cheng, LIN Po-rung, CHEN Tsai-ning, YU Ting-en, WUU Dong-sing. Growth of Al-doped ZnO Window Layer for GaN LED Application[J]. Chinese Journal of Luminescence, 2008,29(3): 508-512
因应新时代电子产品的需求
透明导电薄膜(Transparent Conductive Oxides
TCO)的应用也更加广泛
传统上是使用氧化铟锡(Indium Tin Oxide
ITO)薄膜为透明导电薄膜
但其在高温应用上较不稳定并且易放出毒性
因此
铝掺杂氧化锌薄膜(ZnO:Al
AZO)有逐渐取代ITO的趋势。本论文将探讨掺杂不同铝含量的影响
并且就其光电特性加以说明
最后得到其光的透过率~85%、电阻率~7.3×10
-3
Ω·cm以及面粗糙度~28nm的铝掺杂氧化锌薄膜
其具有表面粗化、电流分布层及窗口层的作用。并且将掺铝的氧化锌薄膜应用于氮化镓发光二极管上
以掺铝氧化锌微结构作为透明传导层的氮化镓发光二极管(λ
D
=530nm
300×300μm)在20mA的工作电流下
其正向电压值为3.3V
输出功率达1.7mW
并且由光学显微镜图可以得知
小电流注下其电流分布均匀。若将AZO制作参数再作适当优化调整
取代ITO作为p型氮化镓上的透明传导层的可行性应该很高。
Effects of Al doping on the morphology and structure of Al-doped ZnO(AZO) were discussed. Analysis of AZO was carried out by scanning electron microscopy
photoluminescence and double-crystal X-ray diffraction. The diffraction peak position of the (002) plane was shifted to a lower angle with increasing Al concentration. It was found that the UV emission peak of near band edge emission in PL has a blue-shift to a region of higher photon energy with increasing Al concentration. The AZO epilayer was used as surface texturing
uniform current spreading
high transparent and thick window layer for achieving a highly efficient LED. AZO was deposited on the GaN-based LEDs as the transparent conducting layer. Light transmission above ~85% in the wavelength ranging from 400 to 700 nm
and AZO resistivity and roughness of ~7.3×10
-3
Ω·cm and ~28 nm were obtained
respectively. The OM image shows that the LED with an AZO layer can reach a uniform current spreading at a relatively low current intensity (~0.02 mA).
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