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赣南师范学院, 化学与生命科学系,江西 赣州,341000
收稿日期:2006-08-25,
修回日期:2006-11-24,
纸质出版日期:2007-05-20
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刘桂荣. Tm<sup>3+</sup>-Yb<sup>3+</sup>共掺杂的碲酸盐玻璃和光纤的光谱特性[J]. 发光学报, 2007,28(3): 354-360
LIU Gui-rong. Spectroscopic Properties of Tm<sup>3+</sup>-Yb<sup>3+</sup>-codoped Tellurite Glasses and Fibres[J]. Chinese Journal of Luminescence, 2007,28(3): 354-360
研究了Tm
3+
-Yb
3+
共掺杂的碲酸盐玻璃和光纤在980nm激光二极管激发下的可见与近红外光谱性质.室温下
Tm
3+
-Yb
3+
共掺杂的碲酸盐玻璃在480
800nm处观测到了很强的上转换发光
在650nm观测到一较弱的上转换发光
它们分别来自Tm
3+
离子的
1
G
4
→
3
H
6
3
H
4
→
3
H
6
和
1
G
4
→
3
F
4
跃迁;在1020
1810nm处观测到近红外发射
它们分别属于Yb
3+
离子的
2
F
5/2
→
2
F
7/2
跃迁和Tm
3+
离子的
3
F
4
→
3
H
6
跃迁.研究了其发光特性与Tm
3+
及Yb
3+
的浓度的依赖关系.此外
在980nm激光激发下
还观测到Tm
3+
-Yb
3+
共掺杂的碲酸盐玻璃光纤在1060
1470
1910nm附近的近红外发射.详细讨论了其发光机制
该材料可望用于制作蓝色上转换光纤激光器、S-波段光纤放大器以及在医疗诊断和遥感中有着广泛的应用的1.9μm光纤激光器.
Upconversion Tm
3+
-doped fibre lasers have recently attracted much interest as compact and efficient blue light source. A CW room temperature upconversion laser at 480nm has been demonstrated. Since the high power laser with several hundreds milliwatts to several watts power at 980nm is commercially avai-lable and Yb
3+
ion has a large absorption cross-section around 980nm
the Tm
3+
Ho
3+
Er
3+
and Pr
3+
ions have successively been excited via the energy-transfer processes in different host by exploiting the Yb
3+
ions as sensitizers for the upconversion processes. On the other hand
the transition
3
F
4
→
3
H
6
of Tm
3+
at 1.8μm has applications in medicine and remote sensing
and consequently it has attracted a lot attention recently. In this paper
the visible and near infrared spectroscopic properties of Tm
3+
-Yb
3+
-codoped tellurite glasses and fibres under the excitation of a 980nm laser diode were investigated. Intense upconversion emissions at 480 and 800nm
and weak emission at 650nm
attributed to
1
G
4
→
3
H
6
3
H
4
→
3
H
6
and
1
G
4
→
3
F
4
transitions of Tm
3+
respectively
were recorded in Tm
3+
-Yb
3+
-codoped tellurite glasses at room temperature. The near infrared emissions at 1020 and 1810nm
which were attributed to transitions Yb
3+
:
2
F
5/2
→
2
F
7/2
and Tm
3+
:
3
F
4
→
3
H
6
respectively
were also observed. The emission characteristics dependence on Tm
3+
and Yb
3+
ions concentrations was also studied. In addition
intense upconversion emissions at 495 and 830nm
and weak emission at 650
and near infrared emissions at 1060
1470 and ~1910nm were recorded in Tm
3+
-Yb
3+
-codoped tellurite fibres using 980nm laser excitation. The luminescence mechanisms are discussed in detail for designing upconverted blue fibre laser
S-band fibre amplifier
and 1.9μm fibre laser for their potential application in clinical diagnosis and remote sensing.
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