LI Jiang, WU Yu-song, PAN Yu-bai, ZHU Yong, GUO Jing-kun. Spectroscopic Properties of Cr<sup>4+</sup>,Nd<sup>3+</sup>:YAG Transparent Ceramics for Self-Q-switched Laser[J]. Chinese Journal of Luminescence, 2007,28(2): 219-224
LI Jiang, WU Yu-song, PAN Yu-bai, ZHU Yong, GUO Jing-kun. Spectroscopic Properties of Cr<sup>4+</sup>,Nd<sup>3+</sup>:YAG Transparent Ceramics for Self-Q-switched Laser[J]. Chinese Journal of Luminescence, 2007,28(2): 219-224DOI:
) crystal is an ideal material used for passive-Q-switch
especially used in high power and high repetition rate lasers. Nd
3+
-doped YAG crystal is the best gain medium at present. Since 1995 Ikesue et al. firstly demonstrated the possibility of fabricating transparent Nd:YAG ceramics of sufficient quality for solid-state lasers
polycrystalline ceramic laser materials have attracted much attention because the optical quality has been improved greatly and highly efficient laser output could be obtained whose efficiencies are comparable or superior to those of single crystal. The purpose of the work is to combine the advantages of the gain medium Nd
3+
and the saturable absorber Cr
4+
using ceramic technology.The transparent Cr
4+
Nd
3+
:YAG ceramics were fabricated by a solid-state reaction and vacuum sintering with CaO as a charge compensator
tetraethyl orthosilicate (TEOS) as a sintering aid and high-purity -Al
2
O
3
Y
2
O
3
Nd
2
O
3
and Cr
2
O
3
powders as starting materials. The absorption spectra
fluorescence spectra and fluorescence of the 0.1%Cr
1.0%Nd:YAG transparent ceramics were measured at room temperature. For the Cr
4+
Nd
3+
:YAG transparent ceramic sintered at 1800℃ for 30h
the absorption cross section
is 4.2710
-20
cm
2
at 808 nm
emission cross section and fluorescence lifetime are 1.5210
-20
cm
2
and 206 s at 1 064 nm
respectively. The laser performance parameters of the gained Cr
4+
Nd
3+
:YAG transparent ceramic were evaluated by
I
sat
min
and
I
min
based on the spectroscopic parameters. The pump saturation intensity parameter
I
sat
the
min
parameter which is defined as the minimum inversion fraction of Nd
3+
ions that must be exited to balance the ions exactly with the ground-state absorption at the extraction wavelength
and the minimum absorption pump intensity
I
min
to reach the threshold at the extraction wavelength are 28.0kW/cm
2
52.2% and 14.6 kW/cm
2
respectively. High-quality Cr
4+
Nd
3+
:YAG transparent ceramics
which combine the gain media and the saturable absorber together
may be a potential self-Q-switched laser material.