LI Bao-zeng, GUO Hai, CHEN Xue-sheng, JIANG Hua, ZHENG Zhi-qiang, MING Hai. Up-conversion Luminescence of Er<sup>3+</sup>and Er<sup>3+</sup>/Yb<sup>3+</sup>Ions Doped PLZT for Active Electro-optical Applications[J]. Chinese Journal of Luminescence, 2007,28(1): 62-66
LI Bao-zeng, GUO Hai, CHEN Xue-sheng, JIANG Hua, ZHENG Zhi-qiang, MING Hai. Up-conversion Luminescence of Er<sup>3+</sup>and Er<sup>3+</sup>/Yb<sup>3+</sup>Ions Doped PLZT for Active Electro-optical Applications[J]. Chinese Journal of Luminescence, 2007,28(1): 62-66DOI:
ceramic laser materials have emerged with many advantages
such as lower cost fabrication
high melting temperature and large size samples more easily to be manufactured
as compared to crystals and glasses.There has been remarkable interest in rare-earth-doped ferroelectric ceramics which are suitable material for novel integrated-optic devices formed by a combination of lasers/amplifier with electro-optic(EO)and nonlinear-optic waveguide components.Recently
a new highly transparent
electro-optic ceramic material
Er
3+
and Er
3+
/Yb
3+
ions doped Pb
1-x
La
x
Zr
y
Ti
1-y
O
3
(PLZT)
have been fabricated
which have exceptionally high electro-optic(EO)effect.The up-conversion luminescence of Er
3+
and Er
3+
/Yb
3+
ions doped PLZT for active electro-optical applications has been investigated.The green light of 540 nm and 566 nm can be observed in Er
3+
doped PLZT.Moreover
their intensity gets stronger along with concentration of Er
3+
.In Er
3+
/Yb
3+
co-doped PLZT
besides the green light of 540 nm and 566 nm
a relatively weak red light of 668 nm can also be observed.To all sample
the nonlinear curves fitting to the relationship between up-conversion intensity and excitation intensity were made
which were concluded that both red emission and green emission were the absorption process of double-photon.And again the character of up-conversion luminescence was discussed using the Raman spectra of PLZT.The theory and experimentation both show Er
3+
and Er
3+
/Yb
3+
ions doped PLZT
based on its large electro-optical effect
have a prospect to be applied for electro-optic Q-switched double-function up-conversion laser device.