LI Xiu-fang, DENG Zhen-bo, ZHANG Yuan-yuan, SHI Yu-meng, WANG Rui-fen. Emission Mechanism in the Tb Complex Doped PVK System[J]. Chinese Journal of Luminescence, 2007,28(1): 39-43
LI Xiu-fang, DENG Zhen-bo, ZHANG Yuan-yuan, SHI Yu-meng, WANG Rui-fen. Emission Mechanism in the Tb Complex Doped PVK System[J]. Chinese Journal of Luminescence, 2007,28(1): 39-43DOI:
and was used as an emitting material in electroluminescence devices.The material was doped into poly N-vinylcarbazole(PVK)as the emitting layer
which is made by spin coating.Three kinds of devices were fabricated with the structures:(A)ITO/PVK:Tb(o-MBA)
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phen/LiF/Al;(B)ITO/PVK:Tb(o-MBA)
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phen/BCP/Alq
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/LiF/Al
(C)ITO/BCP/PVK:Tb(o-MBA)
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phen/Alq
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/LiF/Al.Bright green emission could be obtained from Device A and Device C.Photoluminescence(PL)and electroluminescence(EL)mechanisms of this material were investi-gated.There is an overlap between the PL spectrum of PVK and the excitation spectrum of the terbium complex
so there should be F rster energy transfer process between them.The excitation spectrum of Tb(o-MBA)
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phen doped PVK system is alike with the excitation spectrum of PVK
yet it is different with that of Tb(o-MBA)
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phen.So the emission of Tb(o-MBA)
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phen should partly come from the excitation of PVK.While in the OLED based on Tb(o-MBA)
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phen
the emission mainly come from the direct recombination of electron and hole.Bright green emission was obtained from the optimized multi-layer Device C and the highest EL brightness reached 180cd/m