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1. 天津理工学院, 材料物理研究所 天津,300191
2. 中国科学院化学研究所, 有机固体重点实验室, 北京, 100080
收稿日期:2004-01-15,
修回日期:2004-03-20,
纸质出版日期:2004-05-20
移动端阅览
郑加金, 华玉林, 印寿根, 冯秀岚, 吴晓明, 王树国, 孙媛媛, 李永舫, 杨春和, 帅志刚. Zn(BTZ)<sub>2</sub>白色有机电致发光材料的合成及其器件制备[J]. 发光学报, 2004,25(3): 231-236
ZHENG Jia-jin, HUA Yu-lin, YIN Shou-gen, FENG Xiu-lan, WU Xiao-ming, WANG Shu-guo SUN Yuan-yuan, LI Yong-fang, YANG Chun-he, SHUAI Zhi-gang. Synthesis of Zn(BTZ)<sub>2</sub> and Fabrication of White Organic Light-emitting Devices[J]. Chinese Journal of Luminescence, 2004,25(3): 231-236
郑加金, 华玉林, 印寿根, 冯秀岚, 吴晓明, 王树国, 孙媛媛, 李永舫, 杨春和, 帅志刚. Zn(BTZ)<sub>2</sub>白色有机电致发光材料的合成及其器件制备[J]. 发光学报, 2004,25(3): 231-236 DOI:
ZHENG Jia-jin, HUA Yu-lin, YIN Shou-gen, FENG Xiu-lan, WU Xiao-ming, WANG Shu-guo SUN Yuan-yuan, LI Yong-fang, YANG Chun-he, SHUAI Zhi-gang. Synthesis of Zn(BTZ)<sub>2</sub> and Fabrication of White Organic Light-emitting Devices[J]. Chinese Journal of Luminescence, 2004,25(3): 231-236 DOI:
以PCl
3
为脱水剂
将邻氨基硫酚与水杨酸脱水环化合成出2-(2-羟基苯基)苯并噻唑
并进一步将所得产物与乙酸锌反应合成出2-(2-羟基苯基)苯并噻唑螯合锌(Zn(BTZ)
2
)材料。以该配合物作为发光层制备出结构为ITO/PVK:TPD/Zn(BTZ)
2
/Al近白色电致发光器件
其色坐标位于白场之内(x=0.242
y=0.359)
在驱动电压为16V时
亮度达3200cdm
2
对应的量子效率为0.32%。进一步在Zn(BTZ)
2
中掺入橙红色染料Rubrene
制成ITO/PVK:TPD/Zn(BTZ)
2
:Rubrene/Al结构器件
实现了纯白色发光(色坐标值:x=0.324
y=0.343)
非常接近于白色等能点
且量子效率达0.47%。最后对上述器件的发光和电学性能进行了深入的研究和探讨。
Bis-2-(2-hydroxyphenyl)benzothiazolate)zinc (Zn(BTZ)
2
) is one of the best white electroluminescent materials used in organic light emitting diodes (OLEDs). White light
which is composed of three discrete peaks in R/G/B regions
is very important and particularly useful for full color display. However
most of white OLEDs
so far
are fabricated with multilayer structures
which results in the complication of fabrication process and decline of quantum efficiency. So these devices are not suitable for the purpose of large scale industrial manufacture. In this paper
firstly
Zn(BTZ)
2
had been synthesized from the complex reaction between zinc acetate dihydrate and 2-(2-hydroxyphenyl) benzothiazolate. Then we used Zn(BTZ)
2
as main light emitting material and fabricated two types of organic white light emitting devices. The configurations of the devices are as follows: ITO/PVK: TPD/Zn(BTZ)
2
/Al and ITO/PVK:TPD/Zn(BTZ)
2
:Rubrene/Al. The bright and steady light emitting had been obtained
and the brightness of the devices came to 3200cd/m
2
and 2900cd/m
2
(at a driving voltage of 16V)
respectively. We also measured the CIE coordinates of the above devices
they were (x=0.242
y=0.359) and (x=0.324
y=0.343)
respectively. The latter CIE coordinate is very close to the equi energy point (x=0.33
y=0.33)
and the corresponding quantum efficiency value is 0.47%. This value is higher than the former one
which is 0.32%. Details on the white light emitting characteristics of the devices were explained by the curves of current den sity voltage
optical current voltage and quantum efficiency current density
they were measured using a quantum efficiency measure system including the Keithley 485 Picoammeter and 2400 SourceMeter. We also discussed the emitting mechanisms of the material and the devices at last.
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