LI Feng, WANG Yu-hua. Photoluminescence Properties of BaMgAl<sub>10</sub>O<sub>17</sub>:Eu Coated with MgF<sub>2</sub> by Sol-gel Process[J]. Chinese Journal of Luminescence, 2004,25(6): 667-672
LI Feng, WANG Yu-hua. Photoluminescence Properties of BaMgAl<sub>10</sub>O<sub>17</sub>:Eu Coated with MgF<sub>2</sub> by Sol-gel Process[J]. Chinese Journal of Luminescence, 2004,25(6): 667-672DOI:
because of the requirement of plasma display panels (PDPs) and a possible new generation of Hg-free lamps
much attention has been paid to phosphors for vacuum ultraviolet (VUV) excitation. BaMgAl
10
O
17
:Eu(BAM) is widely used as a blue emitting commercial phosphor for plasma display panels (PDP) and used in Hg-free lamp due to its high efficiency and good chromaticity. However
BAM suffers a thermal degradation during the manufacturing of PDP and a lifetime degradation during PDP operation. Thus the application of BAM in PDP is hindered. In Hg-free lamps
the degradation of BAM is mainly caused by thermal treatment during lamp manufacturing. One of the options to enhanced thermal stability and ion resis-tance for BAM is the application of a closed particle coating. Among the coating materials
MgF
2
is preferable for its high secondary electron emission coefficient and low refractive index in the range from 130 nm to 7400 nm. In this work
a sol-gel process was applied to coat BAM phosphors with MgF
2
which is low apparatus-dependent compared with other processes
using trifluoroacetic acid (TFA) and magnesium acetate as precursors. The coatings were characterized by XPS and SEM. Their anti-thermal degradation and photoluminescence properties were investigated under UV and VUV excitation. The results indicated that BAM phosphors were successfully coated with MgF
2
-coatings and the coated BAM was much more stable than the uncoated when both fired at 600℃ for 30 min in the air. The optimum anti-thermal degradation properties were obtained at the mass ratio 0.2% under 254 nm excitation and 0.5% under 147 nm excitation
respectively. As a conclusion
the sol-gel coating process is a promising method to protect the phosphor powders
and improves the phosphors anti-thermal degradation properties under UV and VUV excitation for application in displays and lamps.