ZHAO Chu-jun, LI Hong-jian, HUANG Bo-yun, YI Dan-qing, YAO Ling-jiang, XU Xue-mei, PENG Jing-cui. Influence of Metal/Organic Interface Barriers on the EL Efficiency in Single-layer Organic EL Devices[J]. Chinese Journal of Luminescence, 2004,25(4): 401-406
ZHAO Chu-jun, LI Hong-jian, HUANG Bo-yun, YI Dan-qing, YAO Ling-jiang, XU Xue-mei, PENG Jing-cui. Influence of Metal/Organic Interface Barriers on the EL Efficiency in Single-layer Organic EL Devices[J]. Chinese Journal of Luminescence, 2004,25(4): 401-406DOI:
An analytical model to calculate the electroluminescence(EL) profile at high electric field in single layer structure
taking into account the charge injection process at each electrode
fission and recombination of polaron-excitons in disordered system
is presented.The influences of the barriers of metal/organic interface on EL efficiency are thoroughly studied.When the barrier exceeds about 0.3eV
the EL efficiency will become very small.While lowering the barrier of metal/organic interface
the EL efficiency will be enhanced.With increasing applied voltages
the injection efficiency increases while the recombination efficiency decreases
and when the electric field increases to a critical value
the EL efficiency reaches the maximum and then decreases.It indicates that the EL efficiency is dominated by injection at lower voltages and recombination at higher voltages.It is found this model can reasonably eluci-dates the influence of injection and recombination processes on EL efficiency
which provides a theory to improve the EL efficiency
to optimize the structure and to select suitable electroluminescent materials.