CHENG Li-hong, CAO Wang-he, XIA Tian. Up-conversion Luminescence of Fluoro-oxide Glass Co-doped with Er<sup>3+</sup> and Yb<sup>3+</sup> under 980nm Excitation[J]. Chinese Journal of Luminescence, 2004,25(4): 355-358
CHENG Li-hong, CAO Wang-he, XIA Tian. Up-conversion Luminescence of Fluoro-oxide Glass Co-doped with Er<sup>3+</sup> and Yb<sup>3+</sup> under 980nm Excitation[J]. Chinese Journal of Luminescence, 2004,25(4): 355-358DOI:
A kind of up-conversion luminescence material with new composition was prepared
the material not only has the higher up-conversion luminescence efficiency
but also avoids the defect of fluoride host material.It consists of 58.52%PbF
2
-34.43%GeO
2
-3%Al
2
O
3
-0.05%Er
2
O
3
-4%Yb
2
O
3
among which GeO
2
acts as the oxide of glass formation
PbF
2
and Al
2
O
3
act as the regulator
and co-doped Er
3+
and Yb
3+
ions are taken as the objects of up-conversion investigation.The up-conversion emissive spectra were measured under 980nm excitation using a semiconductor laser diode
the very strong red light of 658nm and green light of 548nm and 526nm can be observed.Moreover
the red light emissive intensity is far stronger than that of the green light one.A nonlinear curve fitting to the relationship between up-conversion emissive intensity and excitation light power was made
it is concluded that both red emission and green emission are the absorption process of double-photon.The relationship between the operation current of 980nm laser diode and up-conversion fluorescence intensity was investigated
and the up-conversion luminescence characteristic was discussed.