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1. 吉林大学集成光电子学国家重点实验室, 吉林, 长春, 130023
2. 吉林师范大学电子信息与工程学院,吉林 四平,136000
收稿日期:2003-04-28,
修回日期:2003-08-26,
纸质出版日期:2004-07-20
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侯晶莹, 姜文龙, 赵毅, 高强, 刘式墉. 一种利用双发光区的有机红光电致发光器件[J]. 发光学报, 2004,25(4): 407-413
HOU Jing-ying, JIANG Wen-long, ZHAO Yi, GAO Qiang, LIU Shi-yong. Realization of Red Organic Light-emitting Diode by Introducing the Double Emitting Zone[J]. Chinese Journal of Luminescence, 2004,25(4): 407-413
针对一般掺杂结构的红光有机电致发光器件效率随外加电压的增加而迅速下降
同时色度逐渐变差的特点
我们引入了在NPB层和Alq
3
层内同时掺杂DCJTB的具有双发光区的器件结构。制备的双发光区掺杂器件在驱动电压8~20V内发光效率只下降了4%;而色度从8V时的(
x
=0.6287
y
=0.3663)变化到20V时的(
x
=0.6075
y
=0.3841);器件的发光亮度从8V时的178cd/m
2
变化到20V时的5962cd/m
2
具有较好的性能水平。观察到器件效率基本上不依赖于外加电压的变化而变化的特性
同时器件也保持一个比较好的色纯度
并对结果进行了分析。
The red organic LEDs with high brightness and good color purity are necessary for the achievement of full-color emission displays.Commonly
the red OLEDs were made by doping the DCJTB into the Alq
3
host due to its stability and charge-transporting ability.But this doped system showed a contrary phenomenon of low efficiency(at high concentrations of DCJTB) or poor color purity(at low concentrations of DCJTB).Meanwhile
the efficiency of these devices declined rapidly after it reached the maximum efficiency point with the applied voltage increasing.Although intensive research has been made in recent years
the performance of red devices is not satisfactory either the luminance efficiencies or the color purity.In this paper
we fabricated organic EL devices with double emitting zone in order to obtain the efficiency independent on the applied vol-tage and together with good color purity.The saturated red organic light-emitting diode(OLED) has been realized by doping an emitting material in the hole-transporting layer(HTL)and electron-transporting layer(ETL) to form double emitting zone.The red dopant
DCJTB
was doped into the NPB layer and Alq
3
layer
which both act as the emitting layer.The optimal device
with a structure of ITO/CuPc/NPB/NPB:DCJTB/Alq
3
:DCJTB/Alq
3
/LiF/Al
showed a good performance of the current efficiency being relatively independent of the drive voltage in a wide range from 8V to 20V(only reduced by 4%)and the chromaticity coordinates changed from 8V(
x
=0.6287
y
=0.3663)to 20V(
x
=0.6075
y
=0.3841)
and the devices maintain a pure red emission.That may be helpful to ameliorate the lifetime of the organic electroluminescence(EL) devices and adjust the gray-scale for the future full-color display panel.
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