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1. 吉林大学, 材料科学与工程学院,吉林 长春,130023
2. 吉林大学, 电子科学与工程学院,吉林 长春,130023
3. 吉林大学, 化学系,吉林 长春,130023
收稿日期:2002-08-11,
修回日期:2002-12-23,
纸质出版日期:2003-07-20
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王欣, 高丽娟, 于陕升, 郑伟涛, 徐娓, 郭巍, 杨开宇. 直流磁控溅射氮化铁薄膜生长的动力学标度[J]. 发光学报, 2003,24(4): 431-434
WANG Xin, GAO Li-juan, YU Shan-sheng, ZHENG Wei-tao, XU Wei, GUO Wei, YANG Kai-yu. Kinetic Scaling of Iron Nitride Thin Films Deposited by DC Magnetron Sputtering[J]. Chinese Journal of Luminescence, 2003,24(4): 431-434
王欣, 高丽娟, 于陕升, 郑伟涛, 徐娓, 郭巍, 杨开宇. 直流磁控溅射氮化铁薄膜生长的动力学标度[J]. 发光学报, 2003,24(4): 431-434 DOI:
WANG Xin, GAO Li-juan, YU Shan-sheng, ZHENG Wei-tao, XU Wei, GUO Wei, YANG Kai-yu. Kinetic Scaling of Iron Nitride Thin Films Deposited by DC Magnetron Sputtering[J]. Chinese Journal of Luminescence, 2003,24(4): 431-434 DOI:
利用直流磁控溅射方法
以Ar/N
2
作为放电气体
通过改变放电气体中N
2
的流量(N
2
流量比分别为5%
10%
30%
50%)及溅射时间(160
30
20
10
5min)
在玻璃衬底上沉积了FexN薄膜。用X射线光电子能谱(XPS)方法确定了不同N
2
流量下薄膜的成分;X射线衍射(XRD)方法分析了不同N
2
流量下的FexN薄膜结构
当N
2
流量比为5%时获得了FeN
0.056
相
10%时为ε-Fe
3
N相
30%和50%流量比下均得到FeN相。利用原子力显微镜(AFM)和掠入射X射线散射(GIXA)方法研究了膜表面的粗糙度和形貌
发现随着N
2
流量的增加
薄膜表面光滑度增加
薄膜表面呈现自仿射性质。动力学标度方法定量分析表明:薄膜表面因不同N
2
流量的影响而具有不同的动力学指数
当氮气流量比为5%时
静态标度指数α≈0.65
生长指数β≈0.53±0.02
薄膜生长符合基于Kolmogorov提出的能量波动概念的KPZ模型指数规律。
Iron nitride films have received attention for many years. Initially
they have been studied because of their ability to improve surface hardness and wear resistance. Recently
the FeN thin films have been widely investigated since they show a variety of structures and magnetic properties. All nitrides with the composition of Fe
x
N(
x
≥3) are ferromagnetic and stable at room temperature. In particular
α″-Fe
16
N
2
phase is the most important compound and can be a possible candidate for high density magnetic recording media owing to its very high magnetic moment even higher than that of pure iron. However
up to now
little research has been done to investigate the dynamical scaling behavior of iron nitride films sputtered on glass to determine its universality class although dynamic scaling may be a useful method for understanding the formation of structure of the thin films. There are three types of growth morphologies:layer by layer growth
unstable growth
and self affine surface. Solid films grown under far from equilibrium conditions are predicted to have self affine surfaces
and the roughness can be characterized by appealing to a dynamic form. Moreover
the KPZ equation has proven to be a universal equation for real surface growth phenomena only on the basis of computer simulations. There is nearly no unambiguous experimental demonstration of KPZ growth. In this study
we deposited iron nitride thin films by DC magnetron sputtering at mixed Ar/N
2
discharges(N
2
fraction of 5%
10%
30%
50%
respectively) and different times(160
30
20
10
5min) in order to study their kinetic scaling behavior. The composition of the films was analyzed using X-ray photoelectron spectroscopy experiment (XPS). The layer phases and surface morphology of the films were characterized using grazing incidence X-ray scattering and X-ray diffraction as well as atomic force microscopy. For the film grown at N
2
fraction of 30% and 50%
the phase of FeN appears
if the N
2
fraction is 10%
the phase of ε Fe
3
N is formed
while the phase of FeN
0.056
occurs for the film deposited at N
2
fraction of 5%. The surface of the films deposited at N
2
fraction of 5% showed a self affine character. The values of roughness exponent α≈0.65 and growth exponent β≈0.53±0.02 are in agreement with the improvised KPZ exponents based on Kolmogorov’s energy cascade concept.
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