WANG Dong-mei, LIN Quan, ZHANG Jun-hu, YANG Bai. Synthesis and Properties Studies of Optical Resins Containing Rare Earth[J]. Chinese Journal of Luminescence, 2003,24(4): 325-334
WANG Dong-mei, LIN Quan, ZHANG Jun-hu, YANG Bai. Synthesis and Properties Studies of Optical Resins Containing Rare Earth[J]. Chinese Journal of Luminescence, 2003,24(4): 325-334DOI:
Composite materials of rare earth metals and polymers are a series of functional materials with many excellent properties and potential application. This review presents the research state over the decades on the preparation of polymers containing rare earth metals in doping-type and bonding-type
and its applications on the fields of optics
electricity
magnetic
catalysis
analysis
etc
. The rare earth compounds were uniformly dispersed into monomers and polymers as dopant in doping type rare earth polymer
while the bonding type rare earth polymers could be synthesized by the following three approaches:In the first approach
lanthanide ions were incorporated with the reactive functional groups such as hydroxyl and carboxyl in the polymer side chains; The second one is that lanthanide ions were coordinated with polymer dentate ligands such as β-diketonates
carboxyl
pyridine
porphyrin and sulfo group; The third one is homopolymerization and copolymerization of the monomers containing lanthanide ions. In addition
some research results in our groups on the synthesis and properties of optical resins containing rare earth compounds were summarized. In our recent work
some binary and ternary rare earth complexes were dispersed into the styrene/methylacrylic acid copolymerization system
and the optical resins possess a high transparency
intense luminescent properties and good mechanical properties were obtained.