MA Lin, HU Jian-guo, WANG Hui-qin, XU Yan. Surface Coating and Luminescence Performance of BAM Phosphor[J]. Chinese Journal of Luminescence, 2003,24(5): 523-526
MA Lin, HU Jian-guo, WANG Hui-qin, XU Yan. Surface Coating and Luminescence Performance of BAM Phosphor[J]. Chinese Journal of Luminescence, 2003,24(5): 523-526DOI:
For solving the problem on the degradation of light efficient of BAM phosphor
BAM phosphor was coated with alumina sol(the diameter of the particle is about 10nm) making an alumina protective film around the individual powder particle of BAM.The surface state and surface component of the coated powder were investigated with SEM and Xps.The alumina film coating rate on the power surface reached to be about 90% and the film layer was found quite stable as it could stand various processes
e.g.
washing with water
coating in lamp tube and baking at high temperature. The BAM phosphor’s luminescence performance was tested and compared to uncoated phosphor. An evident improvement has been found in the thermal stability. The thermal deterioration of the phosphor was alleviated obviously after annealing at 500
550
600 and 650℃ for 30min. By the way
the fluorescent lamps of single colour were prepared using the coated phosphor for the time lighting test. The degradation of light efficient was less than uncoated one evidently. For example
the degradation of the lamps after lighting for 1 000h
for the coated BAM phosphor was 6.1%
but 18.5% for uncoated one. The mercury amount adsorbed on the phosphor was determined by cold vapour atomic absorption spectrometry(CVAAS)
and the result proved that the adsorbed amount on coated BAM phosphor was evidently less than that for uncoated one. Based on a series of results in the test
it was proved that the coating treatment of BAM phosphor can protect the phosphor powder and can improve the thermal stability and alleviate the decrease in luminance of the BAM phosphor. Therefore
the study by coating treatment for BAM phosphor with alumina sol is of significance in practice.