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1. 中山大学, 光电材料与技术国家重点实验室,广东 广州,510275
2. 中山大学, 化工学院化学系,广东 广州,510275
3. 广东省显示材料与技术重点实验室,广东 广州,510275
收稿日期:2002-10-30,
修回日期:2003-04-15,
纸质出版日期:2003-07-20
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刘彭义, 许宁生, 赵福利, 邓少芝, 陈军, 叶建青, 龚孟濂. ZnqCl<sub>2</sub>薄膜与器件的制备及其光电特性[J]. 发光学报, 2003,24(4): 412-416
LIU Peng-yi, XU Ning-sheng, ZHAO Fu-li, DENG Shao-zhi, CHEN Jun, YE Jian-qing, GONG Meng-lian. Preparation and Photoelectric Properties of ZnqCl<sub>2</sub> Thin Films and Devices[J]. Chinese Journal of Luminescence, 2003,24(4): 412-416
刘彭义, 许宁生, 赵福利, 邓少芝, 陈军, 叶建青, 龚孟濂. ZnqCl<sub>2</sub>薄膜与器件的制备及其光电特性[J]. 发光学报, 2003,24(4): 412-416 DOI:
LIU Peng-yi, XU Ning-sheng, ZHAO Fu-li, DENG Shao-zhi, CHEN Jun, YE Jian-qing, GONG Meng-lian. Preparation and Photoelectric Properties of ZnqCl<sub>2</sub> Thin Films and Devices[J]. Chinese Journal of Luminescence, 2003,24(4): 412-416 DOI:
用热蒸发技术成功地制备了新合成的二氯取代的八羟基喹啉锌(ZnqCl
2
)薄膜
并制作成有机发光器件。紫外吸收谱分析表明
器件在225
290
350
392.5nm处有4个吸收峰。光致发光和电致发光研究表明
ZnqCl
2
薄膜有良好的发光特性
器件的发光亮度大。并分析了ZnqCl
2
薄膜的能级结构。
Organic/polymeric electroluminescence (EL) has attracted much attention because of their potential applications in large-area full-color flat-panel displays. Since the first high performance bilayer organic light-emitting device (OLED) was reported by C. W. Tang in 1987
much progress has been made rapidly in this field. Various novel materials have been synthesized
and many significant devices have been fabricated
and application of OLEDs has been realized in commercial automotive audio system and cellular telephone. However
the efficiency and lifetime of the devices still have to be improved. Developing new type organic light-emitting materials will play an important role on overcoming the current problem. Whereas the choice of materials is very important because it decides directly the OLEDs’ performance. So study on new organic materials is the key to improve light-emitting coefficient and long lifetime. OLEDs were made up of polymer or small molecular compound. However
the polymers are usually spin coated
so it is difficult to avoid pint holes and impurities and their influence on the characteristic of light-emitting devices. The small molecule
Alq
3
as a typical one
can be vacuum deposited and therefore the films with high purify
high fluorescent efficiency
high crystallizing temperature
stable performance can be achieved
which is important to the fabrication of OLEDs. Whereas it is expected to obtain a compound that has a resemble structure with Alq
3
excellent stability and luminescence properties. In this paper
a new light-emitting material ZZnqCl
2
was synthesized; ZZnqCl
2
thin films were deposited by using thermal deposition technique. Light emitting devices were prepared using ZZnqCl
2
as light-emitting layer. There has not been any report on this type of compound so far to our knowledge. The details of an experimental study on the deposition process of ZZnqCl
2
thin films and devices
and their photoelectric properties were given in this paper. It is demonstrated that such films can be deposited by convenient thermal evaporating technique
and a light-emitting devices is prepared successfully. The films were characterized by ultraviolet spectroscopy (UV)
and photoluminescent spectroscopy. Optical absorption and fluorescent spectra of the films were measured. Significant fluorescence was detected and the spectrum was recorded in which two peaks at 406.4
540nm were observed respectively.
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