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1. 北京市太阳能研究所 北京,100083
2. 中国科学院广州能源所, 广东, 广州, 510070
收稿日期:2002-08-12,
修回日期:2002-11-30,
纸质出版日期:2003-05-20
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许颖, 励旭东, 王文静, 于元, 赵玉文, 沈辉. 低成本衬底上多晶硅薄膜电池的探索[J]. 发光学报, 2003,24(3): 301-304
XU Ying, LI Xu-dong, WANG Wen-jing, YU Yuan, ZHAO Yu-wen, SHEN Hui. Polycrystalline Silicon Thin Film Solar Cells on Low Cost Substrates[J]. Chinese Journal of Luminescence, 2003,24(3): 301-304
在低成本、两种纯度的P
++
颗粒硅带衬底(SSP)上
采用RT化学气相沉积(CVD)技术制备了多晶硅薄膜电池。无论高纯硅粉还是低纯硅粉制备的SSP衬底杂质含量都很高且表面凹凸不平;采用4μm/min的沉积速率和钝化作用得到了高质量外延多晶硅薄膜。通过扩散工艺制成的多晶硅薄膜太阳电池的转换效率分别为6.25%(高纯硅粉制成的SSP衬底)和4.5%(低纯硅粉制成的SSP衬底)。
The development of polycrystalline silicon thin film on low cost substrates for solar cells is showing an urgent need to reduce cost. In order to achieve high quality
large grains silicon films
high temperature processes have to be used. So the substrates must be high temperature resistant
and fulfill requirements concerning thermal expansion
chemical and mechanical stability. Up to now
silicon based materials are the best choice to satisfy the requirements mentioned above. In this paper
low cost SSP substrates are chosen for our thin film solar cells. SSP substrates are manufactured by melting silicon powder by Fraunhofer institute of solar energy system
Germany. Two kinds SSP substrates
made from high purity silicon powder and from homemade low purity silicon powder
are used in our experiments. The morphology of SSP substrates were measured by using SEM.It can be seen that either made from high purity silicon powder or from homemade low purity powder has very rough surface. The average grain size is about 50~100μm. AES and ICPAES reveal that there are O
B
Fe
Mn and Cr impurity in the low purity SSP substrates and the concentration of Fe and Cr exceed 10
17
cm
-3
.High purity SSP substrates have 3%~4% oxygen also. The cell's fabrication processes include:substrate treatments; epitaxy of polycrystalline silicon thin film using rapid thermal chemical vapor deposition (RTCVD); emitter formation; front and rear contacts fabricating; anti reflection coating (ARC) deposition. The resistivity characteristics of the epitaxial thin film was 0.1Ω·cm. Hall mobility is 20~70cm
2
/V·s.Film thickness is 20~50μm and average grain size are 50~100μm.The largest growth rate is 5μm/min. The best thin film solar cell's conversion efficiency of 6.36% and 4.5% (AM1.5
25℃
1cm
2
) have been achieved on high and low purity substrate. These results show that low cost thin film solar cells have great potentialities. Although anti reflect coating (ARC) fabrication improves cells' performance obviously (cell's efficiency increases 14%~22% with SiN)
PC1D calculation shows that the best ARC can increase cell's efficiency 40%
that means our cell's ARC is not optimized. Additionally
the cell's efficiencies increases 4%(some results reach 10%~15%) after 30 minutes forming gas annealing in low temperature. That contributes to reduction of contact resistance and partial passivation of grain boundaries and defects. In conclusion
the polycrystalline silicon thin film solar cells on SSP substrates shows a potential way to reduce the cost of solar cells. Further research will be done in our laboratory.
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