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上海大学, 材料科学与工程学院, 上海, 201800
收稿:2002-10-25,
修回:2002-12-28,
纸质出版:2003-05-20
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郑新友, 吴有智, 朱文清, 蒋雪茵, 张志林, 许少鸿. 联苯乙烯类蓝色发光材料DPVBi的合成及发光性质研究[J]. 发光学报, 2003,24(3): 265-269
ZHENG Xin-you, WU You-zhi, ZHU Wen-qing, JIANG Xue-yin, ZHANG Zhi-lin, XU Shao-hong. Synthesis and Luminescent Properties of Distyrylarylene Derivative Blue Emitting Material DPVBi[J]. Chinese Journal of Luminescence, 2003,24(3): 265-269
郑新友, 吴有智, 朱文清, 蒋雪茵, 张志林, 许少鸿. 联苯乙烯类蓝色发光材料DPVBi的合成及发光性质研究[J]. 发光学报, 2003,24(3): 265-269 DOI:
ZHENG Xin-you, WU You-zhi, ZHU Wen-qing, JIANG Xue-yin, ZHANG Zhi-lin, XU Shao-hong. Synthesis and Luminescent Properties of Distyrylarylene Derivative Blue Emitting Material DPVBi[J]. Chinese Journal of Luminescence, 2003,24(3): 265-269 DOI:
合成了联苯乙烯类蓝色有机发光材料DPVBi[4
4'二(2
2二苯乙烯基)1
1'联苯]
用
1
HNMR
IR
元素分析等方法对其结构进行了表征。以DPVBi作发光层制备了电致发光器件
其结构为:ITO/CuPc/NPB/DPVBi/Alq
3
/LiF/Al
研究了器件的电致发光性质。器件最高亮度达4373cd/cm
2
最大流明效率为124lm/W
在20mA/cm
2
电流密度驱动下的亮度为434cd/cm
2
CIE色坐标为x=015
y=016
器件的蓝色发光具有较好的色纯度。重点对器件发光色度的稳定性进行了研究
结果表明
随电流密度(4~4000mA/cm
2
)的变化
器件色度具有很好的稳定性。
Organic electroluminescent (OEL) materials have recently attracted much interest due to their intriguing physical properties and potential applications to flat panel display. Blue EL emitter is essential for the development of a full color display based either on the "color changing medium" technology or the RGB filtered white emission. Many blue organic EL materials have been investigated by a number of researchers. Among them
the most promising ones are DSA derivatives. These classes of compounds generally offer many attractive properties such as high thermal stability and good film forming ability
etc. In this paper
the DSA derivative blue emitting material 4
4' bis(2
2 diphenylvinyl) 1
1' biphenyl
i.e .
DPVBi is synthesized via the Wittig Horner reaction
and determined by IR
1
H NMR and elementary analysis. The photoluminescence(PL) of this compound in solid film and EL have been studied. DPVBi is intense blue fluorescent material and have a good film forming ability. The excitation and emission spectra of the vacuum deposited film of DPVBi have been studied. The emission spectrum shows the emission lies in the blue region with a peak at 460nm under the excitation of 360nm light. A blue organic light emitting diode(OLED) with the structure ITO/CuPc/NPB/DPVBi/Alq
3
/LiF/Al is studied. The EL spectrum of the device is similar to the PL spectrum of single layer DPVBi
indicating that the emission from the device resulted from the same excited state of the DSA derivative. The CIE chromaticity coordinates of the device are x =0.15
y =0.16
showing a very good blue purity. For the blue device
maximum luminance
the luminance under current density of 20mA/cm
2
and luminous efficiency are 4373cd/m
2
434cd/m
2
and 1.24lm/W
respectively. Particularly
it can be found that the CIE chromaticity coordinates of the device can keep better stability all the time with increasing current density as well as showing a very good blue purity. Because the stability of chromaticity is one of the most important factors to practical application of OLEDs
and DPVBi is a stable blue light emitter
it is suitable for applications to flat panel display.
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