LIU Chun-xu, ZHANG Jia-hua, LIU Jun-ye. Study on Superradiation and Z-scan of Nanostructure PIC-I Aggregates[J]. Chinese Journal of Luminescence, 2003,24(2): 199-202
LIU Chun-xu, ZHANG Jia-hua, LIU Jun-ye. Study on Superradiation and Z-scan of Nanostructure PIC-I Aggregates[J]. Chinese Journal of Luminescence, 2003,24(2): 199-202DOI:
Molecular aggregates have the potential applications on nonlinear optics and integrated optics. Unique properties of one dimension nanostructure dye molecular J-aggregates are different from either monomers or bulk materials. The unique optical properties of molecular aggregates
not observed in crystals are superradiant emission and giant optical nonlinearities. Superradiance is caused by the fact that the oscillator strengths of the coupled molecules are swept together in a few eigenstates
which thus obtain agiant transition dipole to the ground state and are therefore superadiant: their radiative decay rate enhanced linearly with the number of coupled molecules N. Absorption of aggregates and superradiance are resonant in the spectra. The nonlinear refractive index
absorption coefficiency and polarizibility were measured with Z-scan.It is observed that three order nonlinear polarizibility was increased with chain lengths shortening and the mechanism was analyzed and discussed.