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1. 中国科学院长春光学精密机械与物理研究所, 激发态物理重点实验室, 吉林, 长春, 130033
2. 内蒙古民族大学, 内蒙古, 通辽, 028043
收稿日期:2002-03-12,
修回日期:2003-08-15,
纸质出版日期:2003-11-20
移动端阅览
张国有, 谢宜华, 赵晓霞, 王芳, 王晓君, 许武. Er<sup>3+</sup>掺杂铌磷酸盐玻璃材料的光谱性质[J]. 发光学报, 2003,24(6): 624-631
ZHANG Guo-you, XIE Yi-hua, ZHAO Xiao-xia, WANG Fang, WANG Xiao-jun, XU Wu. Spectroscopic Properties of Er<sup>3+</sup> Doped Novel Phosphate Glasses[J]. Chinese Journal of Luminescence, 2003,24(6): 624-631
张国有, 谢宜华, 赵晓霞, 王芳, 王晓君, 许武. Er<sup>3+</sup>掺杂铌磷酸盐玻璃材料的光谱性质[J]. 发光学报, 2003,24(6): 624-631 DOI:
ZHANG Guo-you, XIE Yi-hua, ZHAO Xiao-xia, WANG Fang, WANG Xiao-jun, XU Wu. Spectroscopic Properties of Er<sup>3+</sup> Doped Novel Phosphate Glasses[J]. Chinese Journal of Luminescence, 2003,24(6): 624-631 DOI:
采用熔融猝灭方法制备了掺杂不同浓度Er
3+
离子的铌磷酸盐玻璃材料
测量了该材料的吸收光谱、发射光谱和荧光寿命。计算了在该玻璃材料中Er
3+
的光学跃迁强度参数
同时计算了部分能级之间光学跃迁的振子强度、跃迁几率以及辐射跃迁寿命。应用两种不同的方法计算了
4
I
13/2
→I
15/2
受激发射截面
结果证明存在的自吸收很小。荧光寿命随浓度的变化关系表明
4
I
13/2
能级的能量传递是电偶极类型的
同时证明在低浓度下该能级的量子效率接近100%。所有这些研究结果表明
该材料可能成为新的集成光学器件材料的候选者。
1.5mm emission from the first excited state to the ground state of Er
3+
is very important for the applications in integrated optics and lasers.And we know that for a given transition of trivalent rare earth ions its properties mainly depends on the surroundings
say
host where the rare earth ions are inside.At this point
in order to find a better host material to incorporate the Er
3+
a lot of kinds of materials
such as sulfide
chloride
fluoride
oxide glasses
and some kinds of crystals have been studied.Finally
amongst these materials the phosphate glass is thought to be a promising candidate for practical application.But there are problems still left to be solved
like chemical stability
lower transition temperature
and so on.In the present paper
a special host glass composition has been designed.Three samples with different Er concentration have been produced.Absorption spectra for these samples have been measured
the calculation results of absorption cross sections for the samples indicated that for a certain transition they are analogous.J-O parameters have been obtained to be 4.4(Ω
2
)
1.3(Ω
4
) and 1.1×10-2cm
2
(Ω
6
).Using the J-O parameters the oscillator strengths
radiative transition probabilities for other transitions and radiative transition lifetimes for some levels have been derived.Emission cross sections for the transition
4
I
13/2
→
4
I
15/2
have been obtained by using absorption spectra data or emission spectra data.A comparison between the emission cross sections derived from different approaches shows that week reabsorption is existent even in the sample containing 5% of Er
3+
this fact implies that Er
3+
doped this kind of material is suitable for the application in integrated optics.Fluorescence decay for the transition
4
I
13/2
→
4
I
15/2
room temperature has been measured for the samples with different Er
3+
concentration.It is shown that for all the samples
its fluorescence decay lines obey the single exponential function.Through some calculations it could be concluded that the interaction type between Er
3+
ions is of electric dipole
and the quantum efficiency for the transition
4
I
13/2
→
4
I
15/2
in our phosphate glass with lower Er
3+
concentration is close to 100%.From the facts above it is expected that our phosphate glass would be an advanced material for the practical applications in integrated optics and lasers.
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