Tang Z K, Li Z M, Xiao X D, Ge W K. Optical Properties of 0.4nm Single-walled Carbon Nanotubes[J]. Chinese Journal of Luminescence, 2002,23(4): 335-340
Tang Z K, Li Z M, Xiao X D, Ge W K. Optical Properties of 0.4nm Single-walled Carbon Nanotubes[J]. Chinese Journal of Luminescence, 2002,23(4): 335-340DOI:
We report the polarized optical absorption and photoluminescence spectra of single-walled 0.4nm carbon nanotubes (SWNTs) arrayed in the channels of an AlPO
4
-5(AFI)single crystal. When the light electric field(
E
) is polarized parallel to the tube direction(
c
)
the absorption spectrum display a sharp peak at 1.37eV with two broad bands at 2.1eV and 3.1eV.The intensities of these absorption bands gradually decrease as the polarization angle is varied from 0°(
E
||
c
) to 90°(
E
⊥
c
).In the
E
⊥
c
configuration
the tube is nearly transparent in the measured energy region of 0.5~4.1eV. The photoluminescence observed around 700nm also shows strong polarization dependence. Under high power excitation using the fundamental frequency of a YAG laser
the sample shows strong nonlinear up-conversion emission around 700nm and high efficient second-harmonic generation. The mechanism of the nonlinear photoluminescence and SHG is not clear yet.