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1. 昆明物理研究所, 云南昆明650223
2. 南开大学物理科学学院光子学中心 天津,300071
收稿日期:2001-09-20,
修回日期:2001-10-25,
纸质出版日期:2002-03-20
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黄晖, 许京军, 王吉有, 张存洲, 姬荣斌, 潘顺臣, 张光寅. MOCVD外延Hg<sub>1-x</sub>Cd<sub>x</sub>Te/Cd<sub>1-y</sub>Zn<sub>y</sub>Te薄膜的光致发光[J]. 发光学报, 2002,23(2): 133-136
HUANG Hui, XU Jing-jun, WANG Ji-you, ZHANG Cun-zhou, JI Rong-Bin, PAN Shun-chen, ZHANG Guang-yin. Photoluminescence ofHg<sub>1-x</sub>Cd<sub>x</sub>Te/Cd<sub>1-y</sub>Zn<sub>y</sub>Te Epitaxial Films Grown by MOCVD[J]. Chinese Journal of Luminescence, 2002,23(2): 133-136
黄晖, 许京军, 王吉有, 张存洲, 姬荣斌, 潘顺臣, 张光寅. MOCVD外延Hg<sub>1-x</sub>Cd<sub>x</sub>Te/Cd<sub>1-y</sub>Zn<sub>y</sub>Te薄膜的光致发光[J]. 发光学报, 2002,23(2): 133-136 DOI:
HUANG Hui, XU Jing-jun, WANG Ji-you, ZHANG Cun-zhou, JI Rong-Bin, PAN Shun-chen, ZHANG Guang-yin. Photoluminescence ofHg<sub>1-x</sub>Cd<sub>x</sub>Te/Cd<sub>1-y</sub>Zn<sub>y</sub>Te Epitaxial Films Grown by MOCVD[J]. Chinese Journal of Luminescence, 2002,23(2): 133-136 DOI:
利用Raman显微镜系统对两块用MOCVD方法在Cd
0.96
Zn
0.04
Te衬底上生长的Hg
0.8
Cd
0.2
Te外延薄膜样品在光谱范围50~5000cm
-1
进行了测量
在其中的一块样品上首次发现了143eV至193eV范围内出现的具有周期结构的光致发光峰
该发光峰对应的能带中心位于Hg
0.8
Cd
0.2
Te外延层导带底上方173eV
在另外一块外延薄膜样品中仅观察到四个Raman散射峰
没有周期结构的发光峰。为了分析上述光致发光的起因
对两块样品进行了X射线的双晶回摆曲线样品结构分析
得出样品在143eV至193eV范围的光致发光峰是由于改进MOCVD生长工艺提高了样品的结构质量所致
通过分析指出该光致发光峰是来源于Hg
0.8
Cd
0.2
Te外延层中的阴性离子空位的共振能级。
The fundamental physical properties of Hg
1-x
Cd
x
Te make it an excellent candidate material for infrared photoelectric detectors. Recently
much attention has been paid to Hg
1-x
Cd
x
films grown by different epitaxial techniques on the substrate Cd
1-y
Zn
y
Te due to the possibility of fabricating large area detectors as well as high precision focal plane array detectors. Investigations of the phonon vibration spectra for Hg
1-x
Cd
x
are necessary to understand the lattice dynamics and to obtain structure information about the material. In this paper
the micro-Raman spectra of two MOCVD Hg
1-x
Cd
x
/Cd
1-y
Zn
y
Te epitaxial film samples were measured at room temperature within the spectral range of 50cm
-1
to 5000cm
-1
. The quasi-periodically micro-photoluminescent structure in the range from 50cm
-1
to 5000cm
-1
was observed for the first time in one sample. The micro-photoluminescence results show that there is an anion vacancy resonance level far up in the conduction band
about 1.73eV above the conduction band edge in Hg
1-x
Cd
x
/Cd
1-y
Zn
y
Te epitaxial film. In the micro-Raman spectrum of another sample four main Raman peaks at 125.3cm
-1
140.8cm
-1
164.8cm
-1
and 265.2cm
-1
were observed. The Raman peak of 125.3cm
-1
belongs to HgTe-like TO
1
phonon vibrational mode
140.8cm
-1
belongs to HgTe-like LO
1
phonon vibrational mode
164.8cm
-1
occurs due to CdTe-like LO
1
phonon vibration
and 265.2cm
-1
come from the two-phonon mode TO
1
(HgTe-like)+LO
1
(HgTe-like). At the same time
X-ray double-crystal rocking curves were also obtained in order to check the structure quality of two samples. Our results definitely show that the quasi-periodically micro-photoluminescent structure is mainly due to the improvement in quality of the Hg
1-x
Cd
x
Te epilayer. The experimental results also demonstrate that micro-photoluminescence technique in micro-Raman system seems to be a good convenient
simple
contactless method to characterize the perfection of Hg
1-x
Cd
x
Te epitaxial films.
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