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上海大学材料学院电子信息材料系, 上海嘉定, 201800
收稿日期:2001-09-17,
修回日期:2001-10-20,
纸质出版日期:2002-01-20
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张志林, 蒋雪茵, 张步新, 朱文清, 郑新友, 吴有智, 许少鸿. 彩色有机薄膜电致发光及动态矩阵显示[J]. 发光学报, 2002,23(1): 1-6
ZHANG Zhi-lin, JIANG Xue-yin, ZHANG Bu-xin, ZHU Wen-qing, ZHENG Xin-you, WU You-zhi, XU Shao-hong. Color Organic Thin Film Electroluminescence and Passive Matrix Display[J]. Chinese Journal of Luminescence, 2002,23(1): 1-6
张志林, 蒋雪茵, 张步新, 朱文清, 郑新友, 吴有智, 许少鸿. 彩色有机薄膜电致发光及动态矩阵显示[J]. 发光学报, 2002,23(1): 1-6 DOI:
ZHANG Zhi-lin, JIANG Xue-yin, ZHANG Bu-xin, ZHU Wen-qing, ZHENG Xin-you, WU You-zhi, XU Shao-hong. Color Organic Thin Film Electroluminescence and Passive Matrix Display[J]. Chinese Journal of Luminescence, 2002,23(1): 1-6 DOI:
研究了绿色、红色、蓝色和白色4种有机薄膜电致发光器件.通过掺杂得到了高稳定性的绿色及红色器件
绿色器件的半寿命达14000小时(初始亮度100cd/m
2
)
红色器件的半寿命为7500小时(初始亮度50cd/m
2
).还研究了具有空穴锁定层及非锁定层的多种不同结构和材料的蓝色及白色器件.研究表明无论蓝色还是白色器件
具有空穴锁定层的器件稳定性较差
老化过程中界面势垒的变化很大.非锁定层的蓝色及白色器件中
新材料JBEM比DPVBi有更优越的性能.JBEM构成的蓝色器件的半亮度寿命为1035小时(初始亮度100cd/m
2
).由JBEM构成的白色器件中
由蓝色及红色掺杂在同一层的器件得到最好的稳定性
其半亮度寿命为2800小时(初始亮度100cd/m
2
)
而且它具有发光颜色不随电流变化而变化的特点.在稳定性改善的基础上研制成功96×60线
分辨率为2线/mm的绿色及白色矩阵显示屏
还利用选择蒸发的方法制造了彩色矩阵屏
设计和研制了驱动及控制电路
实现了动态显示.
Green
red
blue and white organic light emitting diodes(OLEDs)were investigated.Remarkable improvement in stability has been demonstrated in doped green and red devices.The QA doped green OLED achieved a long life time of 14 000 hours at initial luminance of 100cd/m
2
.The red OLED doped with red dye DCJTB showed high stability
the half decay time reached 7 500 hours at the initial luminance of 50cd/m
2
.Three blue device were constructed as following:ITO/CuPc/NPB/TPBi/Alq/MgAg(Cell BT);ITO/CuPc/NPB/DPVBi:Perylene/Alg/Alq/MgAg(Cell BD);ITO/CuPc/NPB/JBEM:Perylene/Alq/MgAg(Cell BJ).Here TPBi is a hole blocking meterial
DPVBi is a blue host
and JBEM is a new blue emitting mate-rial.On basis of the blue devices
putting the red dopant DCJTB into blue material TPBi
DPVBi
JBEM
or green host Alq
four white devices were produced.Experimental shows that the blue cell and white cell with blocking layer TPBi had much shorter life time than that of the conventional cell.It is obvious that the blocking layer is not favorable to the stability of the device
it may be attributed to the high barrier between the hole transporting and blocking layers.For the blue devices with JBEM as the host or DPVBi as the host
the former has better stability than the latter
showing the life time of 1 035 hours at initial luminance of 100cd/m
2
.For the white OLEDs
just like the blue devices
the cell with JBEM as the host had better performance than that with DPVBI as the host
and the device with blue dye and red dye DCJTB in the same layer showed high stability
the half decay time reached 2846 hours at initial luminance of 100cd/m
2
.A green
white panel display with 96×60 pixels and resolution of 2 lines/mm are constructed.The driving circuit was designed to eliminate the cross-talk between the pixels
a good image was realized.
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