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1. 上海大学材料科学与工程学院, 上海, 201800
2. 中国科学院理化技术研究所, 北京, 100101
收稿日期:2001-09-20,
修回日期:2001-10-26,
纸质出版日期:2002-01-20
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张步新, 马昌期, 蒋雪茵, 张志林, 张宝文, 许少鸿. 基于新型有机红色材料的薄膜电致发光[J]. 发光学报, 2002,23(1): 21-24
ZHANG Bu-xin, MA Chang-qi, JIANG Xue-yin, ZHANG Zhi-lin, ZHANG Bao-wen, XU Shao-hong. Organic Thin Film Electroluminescent Device Based on a Novel Red Material[J]. Chinese Journal of Luminescence, 2002,23(1): 21-24
张步新, 马昌期, 蒋雪茵, 张志林, 张宝文, 许少鸿. 基于新型有机红色材料的薄膜电致发光[J]. 发光学报, 2002,23(1): 21-24 DOI:
ZHANG Bu-xin, MA Chang-qi, JIANG Xue-yin, ZHANG Zhi-lin, ZHANG Bao-wen, XU Shao-hong. Organic Thin Film Electroluminescent Device Based on a Novel Red Material[J]. Chinese Journal of Luminescence, 2002,23(1): 21-24 DOI:
对一种名为N
N双[4[2(4二氰甲烯基6甲基)4H吡喃2基]乙烯基]
苯基苯胺的新型有机红色材料(BDCM)进行了薄膜发光行为的研究.此材料的一个三苯胺(给电子基)和两个二氰甲烯吡喃(受电子基)所形成的较好空间位阻和强荧光发射能力
使得其固体薄膜具有很高的红色荧光量子产率.所构成的ITO/CuPc/DPPP/BDCM/Mg:Ag红色薄膜电致发光器件在外加电压为19V时亮度达到582cd/m
2
.且此器件的发光颜色不随外加电流密度的改变而变化
表明此材料有很好的电子传输和红色发射性能
Bright and efficient organic electroluminescent(EL)devices have attracted considerable interest due to their potential application to flat panel display.To realized full color display applications
the three elemental colors of red
green
and blue emitters with sufficiently high luminous and color purity are necessary.After the last two decades of intensive research
a number of green and blue emitters with high luminance
high efficiency
saturated emission
and practical lifetimes have been developed.However
the corresponding development of the red emitters lags significantly behind that for the other two primary colors.Doping a red dye into a suitable host makes most high-performance of red EL devices.Nevertheless
the low efficiency at high doping concentration is due to the concentration quenching effect
which is common in fluorescence dopants.This problem can be avoided by using host red emitting materials
which can be used as emitting layer as well as hole or electron transport layer.In this paper
a novel red luminescent material N
N-bis-[4-[2-(4-dicyanomethylene-6-methyl-4H-pyran-2-yl)ethylene]phenyl]
aniline(BDCM)with two electron-acceptor moieties(4-dicyanomethylene)pyran and an electron-donor moiety triphenylamine for application in organic EL devices was reported.The resultant compound has a sterically well-hindered structure and a high fluorescence yield.Its photoluminescence(PL)of this compound in solid film and EL have been studied.Based on its intense sterically hindered structure
the pure BDCM film prepared shows a bright red PL emission.The EL device with a structure of indium tin oxide(ITO)/copper phthalocyanine(CuPc)/1
3-diphenyl-5-(1-phenanthreneyl)-2-pyrazoline(DPPP)/BDCM/Mg:Ag shows a bright red emission and a brightness of 582cd/m
2
at a driving voltage of 19V.And it can be found that CIE chromaticity coordinates of the device are nearly unchanged with increasing current density.As expected
the rigidity and non-planar structure of triphenylamine moiety offers BDCM a sterically well-hindered feature
and consequently an excellent pure red emission is obtained even for the pure BDCM.Further
the presence of two electron-acceptor moieties increase the electron affinity of BDCM
and as a result
grant the BDCM efficient electron injection and transport abilities.The combination of above advantages
as the result of incorporating triphenylamiline and two(4-dicyanomethylene)pyrane moieties into one molecule make BDCM serve as host red emitter possible.aniline(BDCM)with two electron-acceptor moieties(4-dicyanomethylene)pyran and an electron-donor moiety triphenylamine for application in organic EL devices was reported.The resultant compound has a sterically well-hindered structure and a high fluorescence yield.Its photoluminescence(PL)of this compound in solid film and EL have been studied.Based on its intense sterically hindered structure
the pure BDCM film prepared shows a bright red PL emission.The EL device with a structure of indium tin oxide(ITO)/copper phthalocyanine(CuPc)/1
3-diphenyl-5-(1-phenanthreneyl)-2-pyrazoline(DPPP)/BDCM/Mg:Ag shows a bright red emission and a brightness of 582cd/m
2
at a driving voltage of 19V.And it can be found that CIE chromaticity coordinates of the device are nearly unchanged with increasing current density.As expected
the rigidity and non-planar structure of triphenylamine moiety offers BDCM a sterically well-hindered feature
and consequently an excellent pure red emission is obtained even for the pure BDCM.Further
the presence of two electron-acceptor moieties increase the electron affinity of BDCM
and as a result
grant the BDCM efficient electron injection and transport abilities.The combination of above advantages
as the result of incorporating triphenylamiline and two(4-dicyanomethylene)pyrane moieties into one molecule make BDCM serve as host red emitter possible.
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