LIU Sheng-li, CHEN Zheng, GUO Shun-zhi. Combustion Synthesis of SrAl<sub>12</sub>O<sub>19</sub>:Eu<sup>2+</sup>[J]. Chinese Journal of Luminescence, 2002,23(6): 604-606
LIU Sheng-li, CHEN Zheng, GUO Shun-zhi. Combustion Synthesis of SrAl<sub>12</sub>O<sub>19</sub>:Eu<sup>2+</sup>[J]. Chinese Journal of Luminescence, 2002,23(6): 604-606DOI:
activated aluminates are efficiently luminescent materials. But they are usually synthesized by solid reaction method
which requires high synthesis temperature and repeated firing in reducing atmosphere
and therefore requires expensive equipment and high consumption of energy. Some synthesis methods which are different from solid reaction method have been used in preparation of aluminate phosphors. The aluminate phosphor
SrAl
12
O
19
:Eu
2+
has been synthesized by the combustion of corresponding metal nitrates and urea at 600℃ furnace temperature
with the excess of urea and a cover above the reaction vessel.The process is energy saving
instantaneous and safe.The product is in hexagonal system and pure phase.The excitation spectrum of the sample is a wide band
of which the strongest peak is at 273nm.The emission spectrum is a band peaking at 395nm.No characteristic excitation and emission of Eu
3+
were observed
showing that the Eu
3+
had been reduced completely. The result showed that an appropriate excess of urea and a relatively airtight reaction system are beneficial to the gain of the pure phase and one color luminescence product in the preparation of Eu
2+
activated aluminate phosphor.When only theoretical amount of urea was added and the cover was not used
the emission of Eu
3+
in the product could be observed.Furthermore
the characteristic emission of Eu
3+
in SrAl
2
O
4
was also seen suggesting that the product is not in pure phase under the later synthesis conditions.