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中国科学院 长春光学精密机械与物理研究所,吉林 长春,中国,130033
收稿:2002-04-12,
修回:2002-5-30,
纸质出版:2002-09-20
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缪国庆, 金亿鑫, 蒋红, 周天明, 李树玮, 元光, 宋航. 生长温度对In<sub>0.53</sub>Ga<sub>0.47</sub>As/InP的LPMOCVD生长影响[J]. 发光学报, 2002,23(5): 465-468
MIAO Guo-qing, JIN Yi-xin, JIANG Hong, ZHOU Tian-ming, LI Shu-wei, YUAN Guang, SONG Hang. Effect of Growth Temperature on Properties of In<sub>0.53</sub>Ga<sub>0.47</sub> As/InP Grown by LPMOCVD[J]. Chinese Journal of Luminescence, 2002,23(5): 465-468
缪国庆, 金亿鑫, 蒋红, 周天明, 李树玮, 元光, 宋航. 生长温度对In<sub>0.53</sub>Ga<sub>0.47</sub>As/InP的LPMOCVD生长影响[J]. 发光学报, 2002,23(5): 465-468 DOI:
MIAO Guo-qing, JIN Yi-xin, JIANG Hong, ZHOU Tian-ming, LI Shu-wei, YUAN Guang, SONG Hang. Effect of Growth Temperature on Properties of In<sub>0.53</sub>Ga<sub>0.47</sub> As/InP Grown by LPMOCVD[J]. Chinese Journal of Luminescence, 2002,23(5): 465-468 DOI:
利用LPMOCVD技术在InP衬底生长了In
x
Ga
1-x
As材料
获得表面平整、光亮的In
0.53
Ga
0.47
As外延层。研究了生长温度对In
x
Ga
1-x
As外延层组分、表面形貌、结晶质量、电学性质的影响。随着生长温度的升高
为了保证铟在固相中组分不变
必须增加三甲基铟在气相中的比例。在生长温度较高时
外延层表面粗糙。生长温度在630℃与650℃之间
X射线双晶衍射曲线半高宽最窄
高于或低于这个温度区间
半高宽变宽。迁移率随着生长温度的升高而增加
在630℃为最大值
然后随着生长温度的升高反而降低。生长温度降低使载流子浓度增大
在生长温度大于630℃时载流子浓度变化较小。
Indium gallium arsenic are now of considerable commercial importance in optoelectronics. For example HBT
HEMTs
FET and Detectors. Very high quality is required to fabricate these devices
in terms of electrical and optical properties. The epilayer properties are known to be very sensitive to growth parameters (growth temperature
Ⅴ/Ⅲ ratio
etc.). It is important to find suitable growth temperature for good quality epilayer properties. The effects of growth temperature on solid composition
surface morphology
crystal quality and electrical properties were investigated for InGaAs. In
0.53
Ga
0.47
As was grown by low-pressure metalorganic chemical-vapor deposition on semi-insulating Fe-doped InP substrate. The substrates were misoriented 2~5° toward (110). Precursors were trimethylindium(TMIn) and trimethylgallium(TMGa) for group Ⅲ
arsine(AsH
3
) and phosphine(PH
3
) for group Ⅴ. The growth temperatures ranged from 500~680℃. Before the epitaxy of InGaAs
an InP buffer layer was grown with 0.1μm. The composition of InGaAs was determined by X-ray diffraction. The surface morphology was examined with SEM. Electrical properties were investigated by Hall effect measurements at room-temperature. The mirror like and featureless morphology of In
0.53
Ga
0.47
As epilayer was attained. In order to keep indium solid composition constant
TMIn vapor composition increase with growth temperature increasing. The pyrolysis temperature of TMGa is higher than that of TMIn which pyrolyzed completely at 500℃. In the range of 500~650℃
the TMGa pyrolysis efficiency increase rapidly with increasing growth temperature. In the range of 650~680℃
because of a larger volatilization rate of indium from surface which is greater than that of gallium
the surface morphology became rough above 680℃. The FWHM of X-ray rocking curve is a good indication of the epilayer quality. A plot the X-ray rocking curve FWHM as a function of growth temperature show a low values between 630℃ and 650℃ but it rises at both higher and lower temperatures. The mobility increase with growth temperature increasing under 630℃. The mobility decrease with growth temperature increasing above 630℃.The best mobility can be obtained at 630℃. At low growth temperature the carrier concentration increase dramatically. This is attributed to enhance carbon incorporation.
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