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暨南大学化学系,广东 广州,510632
收稿日期:2000-08-11,
修回日期:2000-11-18,
纸质出版日期:2001-02-28
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刘应亮, 冯德雄, 杨培慧, 陈喜德, 雷炳富. BaMgAl<sub>10</sub>O<sub>17</sub>:Eu<sup>2+</sup>, RE(RE=稀土)荧光体的燃烧法合成和发光性质[J]. 发光学报, 2001,22(1): 16-19
LIU Ying-liang, FENG De-xiong, YANG Pei-hui, CHEN Xi-de, LEI Bing-fu. Combustion Synthesis and Luminescent Properties of Polyaluminates BaMgAl<sub>10</sub>O<sub>17</sub> Co-activated by Eu<sup>2+</sup> and Rare Earth Ions[J]. Chinese Journal of Luminescence, 2001,22(1): 16-19
刘应亮, 冯德雄, 杨培慧, 陈喜德, 雷炳富. BaMgAl<sub>10</sub>O<sub>17</sub>:Eu<sup>2+</sup>, RE(RE=稀土)荧光体的燃烧法合成和发光性质[J]. 发光学报, 2001,22(1): 16-19 DOI:
LIU Ying-liang, FENG De-xiong, YANG Pei-hui, CHEN Xi-de, LEI Bing-fu. Combustion Synthesis and Luminescent Properties of Polyaluminates BaMgAl<sub>10</sub>O<sub>17</sub> Co-activated by Eu<sup>2+</sup> and Rare Earth Ions[J]. Chinese Journal of Luminescence, 2001,22(1): 16-19 DOI:
应用燃烧法在空气中在较低的温度(600℃)下成功地合成了铝酸盐荧光体BaMgAl
10
O
17
:Eu
2+
RE。并研究了稀土离子对荧光体发光的影响和作用
第一次观察到荧光体的长余辉发光现象。
In the past
the blue component of three colors lamp
BaMgAl
10
O
17
:Eu
2+
was prepared by high temperature solid state method.This paper focuses on the rapid preparation of the phosphors BaMgAl
10
O
17
:Eu
2+
RE(RE=rare earth) by combustion method in air at 600℃ and on the effect of rare earth ions on the properties of the blue phosphor BaMgAl
10
O
17
:Eu
2+
.The XRD analysis shows that the
d
values and relative intensity(
I/I
0
)values of the phosphors BaMgAl
10
O
17
:Eu
2+
RE accord with the standard values in JCPDS card.The structure of the phosphors belongs to hexagonal symmetry.This argues that the combustion synthesis of the blue phosphors BaMgAl
10
O
17
:Eu
2+
RE is feasible and effective.In addition
compared to the high temperature solid state reaction
this combustion procedure has advantages of producing the phosphors with smaller particle size
uinform distribution
higher specific surface area and highly efficient luminescence
and synthesis of the phosphors activated by low value state rare earth ions such as Eu
2+
has no use for hydrogen or carbon power as reduction atmosphere.The excitation and emission spectra and the phosphorescence decay curves of the phosphors are measured and analyzed.The excitation and emission spectra are identical with that of the phosphors prepared by solid state reaction.The effect of rare earth ions on Eu
2+
luminescence is as follows.Only the luminescence of Ce
3+
Gd
3+
Tb
3+
are observed in the host BaMgAl
10
O
17
among all three-value state rare earth ions.When co-doped with Eu
2+
and three-value state rare earth ions
the luminescence of other three-value state rare earth ions are not found in the host except Ce
3+
which has very weak luminescence.This is due to the strong absorption of Eu
2+
restraining the excitation and emission of Ce
3+
Gd
3+
Tb
3+
ions.In addition
the long lasting phosphorescence in those phosphors co-activated by Eu
2+
and Pr
3+
、Nd
3+
、Dy
3+
、Ho
3+
、Er
3+
are observed for the first time.But the position of phosphorescence of Eu
2+
is 489nm
red shift accounts to 39nm compared to the normal spectral peak position of Eu
2+
in BaMgAl
10
O
17
:Eu
2+
.Further studies on the mechanism of phosphorescence and emission position shift are in progress.
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