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1. 中国科学院长春光学精密机械与物理研究所, 吉林, 长春, 130021
2. 宁波大学光电子材料研究所, 浙江, 宁波, 315211
纸质出版日期:2001-11-30
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夏海平, 宋宏伟, 章践立, 陈红兵, 王金浩, 张新民, 聂秋华. 掺杂Er<sup>3+</sup>多组份氧化物玻璃的制备与发光特征的研究[J]. 发光学报, 2001,22(4): 384-388
XIA Hai-ping, SONG Hong-wei, ZHANG Jian-li, CHEN Hong-bing WANG Jing-hao, ZHANG Xin-min, NIE Qiu-hua. Preparation and Infrared Optical Spectroscopy of Multicomponent Oxide Glasses Doped with Er<sup>3+</sup> Ion[J]. Chinese Journal of Luminescence, 2001,22(4): 384-388
夏海平, 宋宏伟, 章践立, 陈红兵, 王金浩, 张新民, 聂秋华. 掺杂Er<sup>3+</sup>多组份氧化物玻璃的制备与发光特征的研究[J]. 发光学报, 2001,22(4): 384-388 DOI:
XIA Hai-ping, SONG Hong-wei, ZHANG Jian-li, CHEN Hong-bing WANG Jing-hao, ZHANG Xin-min, NIE Qiu-hua. Preparation and Infrared Optical Spectroscopy of Multicomponent Oxide Glasses Doped with Er<sup>3+</sup> Ion[J]. Chinese Journal of Luminescence, 2001,22(4): 384-388 DOI:
用高温熔融法制备了用于1.5μm光波段元件高浓度Er
3+
掺杂的B
2
O
3
-SiO
2
Al
2
O
3
-SiO
2
-CdO与Li
2
O-Al
2
O
3
-SiO
2
三种多组分氧化物玻璃.在488nm连续氩离子激发下
测定并比较了这三种玻璃在1.5μm波段的发射光谱特性
及掺杂浓度对发光强度的影响.研究结果表明:Er
3+
:Li
2
O-Al
2
O
3
-SiO
2
具有较宽的发光带
是合适的光放大器玻璃基质材料;而B
2
O
3
-SiO
2
玻璃系统随Er
3+
掺杂浓度的增加
其荧光效应成线性增强
是合适的发光基质.
Trivalent erbium doped glasses are attracting extensive interest due to its potential application in various optical devices such as optical communication
display and lasers.In this paper
the preparation and the infrared luminescent properties of some erbium doped oxide glasses were reported.High erbium doped three multicomponent oxide glasses
B
2
O
3
-SiO
2
Al
2
O
3
-SiO
2
and Li
2
O
3
-Al
2
O
3
-SiO
2
were fabricated by the technique of high-temperature melting.The infrared emission spectra of erbium in the glasses were measured under the excitation of a 488nm argon ion laser.The influence of the host composition and the erbium-concentration on infrared luminescent property at 1.5μm was studied.The results indicate that the emission in-tensity varies remarkably in different hosts.Among the glasses
the emission of erbium in the B
2
O
3
-SiO
2
glass is strongest
while that in the Al
2
O
3
-SiO
2
-CdO glass is the weakest.In addition
the emission intensity of B
2
O
3
-SiO
2
glass doped with erbium increases almost linearly with the erbium concentration
which is favorable for luminous material.In all the glasses
the emission intensity at 1.5μm increases with the erbium concentration
indicating that the concentration-quenching effect is small as the erbium concentration is lower than 2wt%.Among the three glasses
the Er
3+
Li
2
O-Al
2
O
3
-SiO
2
one has a widest emission band at 1.5μm.The global line width of erbium in this glass is as wide as 61.1nm due to the disordered local struc-ture surrounding the erbium ions.Therefore
it is expected to be a deal glass for optical waveguide amplifiers.By contrast to the components of the three glasses
it can be concluded that the global line width of erbium is probably broadened due to the co-doping of Li
2
O in the Al
2
O
3
-SiO
2
glass
although the detail origin is not clear.
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