HUANG Li-hui, LIU Xing-ren, XU Mai. Optical Transitions of Er<sup>3+</sup> in Cd<sub>3</sub>A1<sub>2</sub>Si<sub>3</sub>O<sub>12</sub> Glass[J]. Chinese Journal of Luminescence, 2001,22(4): 362-366
HUANG Li-hui, LIU Xing-ren, XU Mai. Optical Transitions of Er<sup>3+</sup> in Cd<sub>3</sub>A1<sub>2</sub>Si<sub>3</sub>O<sub>12</sub> Glass[J]. Chinese Journal of Luminescence, 2001,22(4): 362-366DOI:
Er-doped glasses have attracted much research interests due to their application in the area of optical communications
such as fiber amplifiers and lasers
and infrared solid-state lasers.To account for the optical absorption and in turn radiative properties of excited states
the Judd-Ofelt theory has been successfully applied to most of the lanthanide ions.In this paper
the experimental and theoretical oscillator strengths of some levels of Er
3+
ion in Cd
3
Al
2
Si
3
O
12
glass(CAS glass in brief) were calculated using the absorption spectra and Judd-Ofelt theory.The root-mean-square deviation is only 3.30×10
-7
.This result indicates that the theory is in well accord with the experiment results.Based on a least-square fit between experimental and theoretical oscillator strengths
the intensity parameters were determined.The results are Ω
2
=6.42×10
-20
cm
2
;Ω
4
=1.53×10
-20
cm
2
;Ω
6
=0.69×10
-20
cm
2
.Then the radiative transition proba-bility A
radiative lifetime r
branching ratio βand integrated emission cross-sections of radiative transitions of Er
3+
in this glass at room temperature were calculated.According to the large integrated emission cross-emission(1.402×10
-18
cm) and the long lifetime(8.062ms) of the transition of
4
I
13/2
→
4
I
15/2
of Er
3+
in CAS glass
it can be concluded 1.534μm laser oscillation of Er-doped CAS glass is possible to be demon-strated.In addition
this glass has several advantages
such as easy-made
scale-varied
easy-fibered and ad-justable host composition along with their high chemical durability and thermal stability.Therefore
Er-doped CAS glass is a potential near infrared solid-state laser material.