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1. 中国科学院长春光学精密机械与物理研究所, 吉林, 长春, 130021
2. 大连海事大学数理系, 辽宁, 大连, 116026
收稿日期:2001-03-22,
修回日期:2001-07-20,
纸质出版日期:2001-11-30
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牛春晖, 曹望和, 臧春雨, 陈宝玖. 掺Er磷酸盐玻璃中红外发光特性研究[J]. 发光学报, 2001,22(4): 357-361
NIU Chun-hui, CAO Wang-he, ZANG Chun-yu, CHEN Bao-jiu. Middle Infrared Luminescence Properties of Er<sup>3+</sup> Doped Phosphate Glass[J]. Chinese Journal of Luminescence, 2001,22(4): 357-361
报道了一种最新型可用于1.5μm光纤通信传输介质的掺Er
3+
的磷酸盐玻璃
通过对其吸收谱的测量
可看到在970nm附近有一很强的吸收峰
适合于采用LD激光泵浦.我们在发射波长为970nm的半导体激光器激发下测量了这种材料的发射谱
观察到在红外波段1540nm处有强发射峰.我们从吸收谱出发拟合出了J-O强度参数
进而计算出了Er
3+
离子各相关跃迁的理论振子强度、实验振子强度及自发辐射系数
从结果可得出理论和实验是相符的.
The amplification of telecommunication signals near 1.5μ m has been successfully demonstrated with Er
3+
doped silica fiber.However
silica fiber is unsuitable as component in short length devices because the highest possible Er
3+
ion concentration in silica fiber is very low around 100ppm.There are several candidates for matrix glasses that homogeneously contain rare earth ions.Phosphate glass is one of these candi-dates.In this paper
we reported a kind of Er
3+
doped phosphate glass which can be used as transmission and amplification medium in 1.5μm optical communication.The phosphate glass is composed of(mol%) P
2
O
5
(60)-Na
2
CO
3
(24)-Al
2
O
3
-Er
2
O
3
(0.5)-Yb
2
O
3
(2.0).Firstly
We precisely measured 10-gram strating materials as showed proportion
then put them into a electric-resistance furnace with temperature of 200℃ for two hours.After those unwanted vapor and gases were got rid of
we transported them into a silica-molybdenum-rod furnace with 1 200℃.When the batch was melted enough about a half hour
we quickly poured the melted liquid into a cube-shaped mould with 480℃ temperature
then put mould into electric-resistance furnace with 480℃ for anneal.The resulting glass cube was cut and polished for spectra experiments.We have measured the absorption spectrum of the galss with PERK IN-ELMER Lambda 9 spectrometer and observed eight absorption bands.Among the eight absorption bands
the absorption band near 970nm was the strongest.Th emission spectrum under 970nm LD excitation has also been acquired.In this spectrum
only a strong emission near 1540nm wavelength can be observed.We have obtained the Judd-Ofelt parameters by fitting the absorption spectrum and got the resutls as follows.Ω
2
=4.29×10
-20
(cm
2
);Ω
4
=1.01×10
-20
(cm
2
);Ω
6
=0.75×10
-20
(cm
2
).The spontaneous emission probabilities of the relevant transition have been calculated with the obstained Judd-Ofelt parameters
so we have a theoretic guide for researching the luminescence phenomenon in the phosphate glass.Lastly
we calculated the absorption and emission cross-section near 1.5μm by Fuchtbaure-Ladenburg theory
from the results we know that the glass has a big emission cross-section near 1.5μm emission.
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