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中国科学院, 上海硅酸盐研究所 上海,201800
收稿日期:2005-11-12,
修回日期:2006-01-18,
纸质出版日期:2006-09-20
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李焕英, 秦来顺, 姚冬敏, 陆晟, 任国浩. Lu<sub>2</sub>Si<sub>2</sub>O<sub>7</sub>:Ce晶体的闪烁性能[J]. 发光学报, 2006,27(5): 729-734
LI Huan-ying, QIN Lai-shun, YAO Dong-min, LU Sheng, REN Guo-hao. Scintillation Properties of Lu<sub>2</sub>Si<sub>2</sub>O<sub>7</sub>:Ce Crystal[J]. Chinese Journal of Luminescence, 2006,27(5): 729-734
李焕英, 秦来顺, 姚冬敏, 陆晟, 任国浩. Lu<sub>2</sub>Si<sub>2</sub>O<sub>7</sub>:Ce晶体的闪烁性能[J]. 发光学报, 2006,27(5): 729-734 DOI:
LI Huan-ying, QIN Lai-shun, YAO Dong-min, LU Sheng, REN Guo-hao. Scintillation Properties of Lu<sub>2</sub>Si<sub>2</sub>O<sub>7</sub>:Ce Crystal[J]. Chinese Journal of Luminescence, 2006,27(5): 729-734 DOI:
用提拉法生长了Lu
2
Si
2
O
7
:Ce晶体
对该晶体的闪烁性能进行了研究。透射光谱表明
Lu
2
Si
2
O
7
:Ce晶体的吸收边比Lu
2
SiO
5
:Ce晶体向短波方向移动了25nm
使透光范围进一步拓宽。X射线发射光谱和UV激发发射光谱均具有典型的双峰特征
主峰在378nm。UV激发发射谱具有温度效应
即375K以上时
发光效率迅速降低;425K以上时
发光主峰位明显红移。衰减曲线符合单指数式衰减规律
常温下经UV激发后的衰减时间约为34ns。从曲线形态看
375K以下的衰减谱与室温下的几乎完全相同
拟合的结果在32.8~34ns之间;衰减时间的温度效应从375K开始显现
即随温度的升高
衰减时间有加速变短的趋势
到500K时缩短为6.72ns。热释光谱在488
553K处有两个热释光峰
但室温附近几乎观察不到热释光峰。
Lu
2
Si
2
O
7
:Ce crystal is a recently discovered inorganic scintillator.It is suitable for applications such as PETor oil well logging.Transparent and crackless LPS:Ce crystals have been grown by using the Czochralski method in our lab.We have characterized the scintillation properties of cerium doped lutetium pyrosilicate and discussed its luminescent mechanism.Alot of work has been done on the temperature dependence of the emission spectra under UVexcitation and the temperature dependence of the fluorescence lifetimes using a Edinburgh-920 luminescence spectrometer
which will help us to find the optimal working temperature for this crystal.Transmission spectra shows that the absorption cut-off edge of LPS:Ce crystal is 25 nm shorter than LSO:Ce crystal
which widens the transmission range.X-ray induced emission spectra are characteristic of two peaks and the main peak locates at 378 nm
which are consistent with the emission spectra under UVexcitation.The temperature dependence of the emission spectra under UVexcitation shows two features
the first is luminescence efficiency decreasing strongly when the temperature beyond 375 K
and the second is peak site red shifting when the temperature beyond 425 K.Decay curve follows the single exponential decay law.The decay time is about 34 ns at room temperature under UVexcitation.Based on the shapes of the decay curves
two distinct trends are identified.First
below 375 K
the curves are similar to that obtained at room temperature
and the fitting results vary from 32.8 ns to 34 ns.There is a little difference
but it is stable on the whole.In this range
the decay time slightly increases with temperature.Second
beyond 375 K
temperature dependence of the fluorescence lifetimes becomes evident
for example
with the increases of the temperature
the decay time strongly decreases.The decay time shorten to 6.72 ns at 500 K.Luminescence efficiency seems connected to decay time
and they change towards the same direction.Two peaks can be observed in TLcurves
approximately situated at 488 and 553 K.Both of them are far above room temperature.No TLglow peaks near room temperature
is suggested to be related to the absence of afterglow in LPS:Ce crystal.
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