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东南大学电子科学与工程学院, 先进光子学中心,江苏 南京,210096
收稿日期:2005-12-28,
修回日期:2006-02-10,
纸质出版日期:2006-09-20
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徐春祥, 徐洪光, 孟瑞平, 冯雪元, 张家雨, 崔一平. 有机吡啶盐的电致发光[J]. 发光学报, 2006,27(5): 679-683
XU Chun-xiang, XU Hong-guang, MENG Rui-ping, FENG Xue-yuan, ZHANG Jia-yu, CUI Yi-ping. Electroluminescence of an Organic Pyridyl Salt[J]. Chinese Journal of Luminescence, 2006,27(5): 679-683
有机盐是一种离子化合物
其分子间依靠比范德瓦尔斯力大得多的离子键结合
这有利于器件稳定性的提高。主要研究一种以新型有机吡啶盐ASPT(trans-4-[P-(N-ethyl-N-(hydroxylethyl)-amino)styryl]-N-methylpyridinium tetraphenyl-borate)作发光层的有机电致发光特性。实验发现有机盐ASPT是一种性能较好的红光发射材料。利用ASPT作发光层的单层电致发光器件
可获得稳定的红色电致发光。通过对外场界面势垒影响分析
我们讨论了这种单层器件的发光机理。为了探索ASPT中载流子传输与复合过程
并提高器件性能
设计了ASPT/Alq
3
双层和TPD/ASPT/Alq
3
三层结构的器件
进一步研究了它们的光电特性。实验结果表明
利用双层器件可获得亮度较高的红色发光。而在三层器件中
由于不同功能层的载流子传输特性的差别
激发复合区域受到驱动电压的显著影响
因此电致发光光谱随电压的变化而变化。通过对光谱结构、能级位置的分析
讨论了相关的发光机理。
Improvement of the triple colors
red
green and blue is the most basic and the most important technology for full color display.Green and blue emission from the organic light emitting diodes (OLED) have been employed successfully to organic display
but the red light performance still need to improved.So far
host-guest system and rare earth complexes were used for red emission.In these two kinds of OLEDs
the energy transfer efficiency were generally limited by the concentration quenching and the phase separation.Ones have paid great effort to explore some novel materials and devices structures for red emission with high perfor-mance.In this paper
an ionic organic pyridyl salt [ASPT (trans-4-[P-(N-ethyl-N-(hydroxylethyl)-amino) styryl]-N-methylpyridinium tetraphenyl-borate) ]
was employed as active layer for an organic light-emitting diode with stable red emission.The investigation on the electroluminescent properties demonstrated that ASPTis a good luminescent molecule for red emission.Astable red electroluminescence was obtained by using this material as emitting layer in a monolayer structure.The luminescence mechanism was discussed based on the influence of the external electrical field on the energy barrier in the interfaces between the active layer and the electrodes.In order to understand the charier charge transport and their recombination process
and to improve the ELperformance
double-layer TPD/ASPTor ASPT/Alq
3
and triple-layer TPD/ASPT/Alq
3
structures were designed and the ELproperties were further studied.Brighter red ELand red-blue variable emission depended on the applied voltage were observed in the double-layer and the triple-layer structures
respectively.Consi-dering the different function of each layer in the triple-layer structure
the color variation is assumed to the change of the recombination region.The mechanism was discussed by analyzing the spectra and the corresponding energy level structures.
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