浏览全部资源
扫码关注微信
1. 宁夏大学, 天然气转化重点实验室,宁夏 银川,750021
2. 泉州七中, 化学教研组,福建 泉州,362000
收稿日期:2005-08-19,
修回日期:2005-11-08,
纸质出版日期:2006-07-20
移动端阅览
雷芳, 徐崇福, 杨敏丽, 房俊卓, 陈昊萍. 溶胶-凝胶法合成蓝色荧光粉SrAl<sub>2</sub>Si<sub>2</sub>O<sub>8</sub>:Eu<sup>2+</sup>[J]. 发光学报, 2006,27(4): 479-483
LEI Fang, XU Chong-fu, YANG Min-li, FANG Jun-zhuo, CHEN Hao-ping. Preparation of Blue Phosphor SrAl<sub>2</sub>Si<sub>2</sub>O<sub>8</sub>:Eu<sup>2+</sup> with Sol-gel Method[J]. Chinese Journal of Luminescence, 2006,27(4): 479-483
雷芳, 徐崇福, 杨敏丽, 房俊卓, 陈昊萍. 溶胶-凝胶法合成蓝色荧光粉SrAl<sub>2</sub>Si<sub>2</sub>O<sub>8</sub>:Eu<sup>2+</sup>[J]. 发光学报, 2006,27(4): 479-483 DOI:
LEI Fang, XU Chong-fu, YANG Min-li, FANG Jun-zhuo, CHEN Hao-ping. Preparation of Blue Phosphor SrAl<sub>2</sub>Si<sub>2</sub>O<sub>8</sub>:Eu<sup>2+</sup> with Sol-gel Method[J]. Chinese Journal of Luminescence, 2006,27(4): 479-483 DOI:
采用溶胶-凝胶(Sol-gel)法以相应的硝酸盐和正硅酸乙酯(TEOS)为反应物在85℃水浴制得胶体
并将干燥后的胶体前驱物在较低温度(921℃)下还原制得蓝色发光材料SrAl
2
Si
2
O
8
:Eu
2+
。分别以热重(TG)-差示扫描量热(DSC)、X射线粉末衍射(XRD)、光致发光(PL)对合成产物进行了表征。并深入研究了溶胶-凝胶法制备过程中的影响因素
如pH值、乙醇含量、柠檬酸含量等
确定了合成SrAl
2
Si
2
O
8
:Eu
2+
的最佳条件。XRD分析表明
当金属离子与柠檬酸的量的比为1:1
无水乙醇的量至少保证TEOS完全溶解于其中
溶液pH值为1.0~2.0时
可得到纯的SrAl
2
Si
2
O
8
六方物相。发光分析表明
产物在监测463nm波长下的激发峰为327nm
在394nm激发下的发射光谱峰为468nm。
Much attention has been paid to search for high-efficient phosphor with the development of displaying device.Some commercial blue phosphors
such as BaMgAl
10
O
17
:Eu
2+
do not meet the ever demanding requirements
they suffer decreasing performance of brightness and color quality because of the serious deterioration.New blue phosphor with stable hosts was belived to be a better way to solve this problem.In the(silicate) host series
Eu
2+
appeared to be a feasible candidate for the blue emitting vehicle originating from(5d-4f)(around 420 nm) transition.SrAl
2
Si
2
O
8
:Eu
2+
a potential excellent blue phosphors suitable for making PDP device and other luminescent apparatus
are conventionally prepared using solid-state reaction at high temperature.However
it is(difficult) to control over particles size and crystal structure at this condition
meanwhile the reaction temperature is so high
serious challenging problems arise to the equipment.Sol-gel method is one of the "soft" chemical methods
which have been employed successfully to prepare phosphor particles with better morphology and(operate) in a lower temperature
compared with solid-state reaction
in recent years.We reported the synthesis of the blue rare earth phosphor SrAl
2
Si
2
O
8
:Eu
2+
by sol-gel method.The sol-gel method was adopted by reacting corresponding nitrate and tetraethylothosilicate(TEOS) at a 85℃ water bath to form a gel
from which the dried precursor was reduced at relatively low temperature of 921℃ to(generate) a blue fluorescence material SrAl
2
Si
2
O
8
:Eu
2+
.The product synthesized was characterized by thermogravimetry(TG)
differential scanning calorimetry(DSC)
X-ray diffraction analysis(XRD)
and fluorescence spectrophotometry.Influential factors in the process of the sol-gel preparation
such as pH value
(ethanol) content
(amount) of citric acid
were studied in depth
and the optimal conditions for synthesizing SrAl
2
Si
2
O
8
:Eu
2+
were determined.XRD analysis indicates that when the mole ratio between citric acid and metal ion was 1:1
the minimal amount of anhydrous ethanol sufficient to secure a total dissolution of tetraethylothosilicate was used
and the pH value between 1.0~2.0 was maintained
the pure SrAl
2
Si
2
O
8
with hexagonal crystal phase could be obtained.The light emitting analysis showed that with the monitoring wavelength 463 nm emission the product gave an exited peak at 327 nm
and an incident light with wavelength 394 nm could generate a fluorescent light with emitting wavelength 468 nm from this phosphor.
0
浏览量
50
下载量
1
CSCD
关联资源
相关文章
相关作者
相关机构