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1. 中国科学院, 激发态物理重点实验室,吉林 长春,130033
2. 中国科学院, 研究生院 北京,100049
3. 中国科学院, 长春光学精密机械与物理研究所,吉林 长春,130033
4. 宁波大学, 光电子功能材料重点实验室,浙江 宁波,315211
收稿:2005-09-27,
修回:2006-3-3,
纸质出版:2006-07-20
移动端阅览
杨艳民, 陈宝玖, 王成, 任国仲, 王晓君, 夏海平. Er<sup>3+</sup>掺杂的Bi<sub>2</sub>O<sub>3</sub>-B<sub>2</sub>O<sub>3</sub>-SiO<sub>2</sub>玻璃的光谱性质[J]. 发光学报, 2006,27(4): 469-473
YANG Yan-min, CHEN Bao-jiu, WANG Cheng, REN Guo-zhong, WANG Xiao-jun, XIA Hai-ping. Spectroscopic Properties of Er<sup>3+</sup> Doped Bi<sub>2</sub>O<sub>3</sub>-B<sub>2</sub>O<sub>3</sub>-SiO<sub>2</sub> Glasses[J]. Chinese Journal of Luminescence, 2006,27(4): 469-473
杨艳民, 陈宝玖, 王成, 任国仲, 王晓君, 夏海平. Er<sup>3+</sup>掺杂的Bi<sub>2</sub>O<sub>3</sub>-B<sub>2</sub>O<sub>3</sub>-SiO<sub>2</sub>玻璃的光谱性质[J]. 发光学报, 2006,27(4): 469-473 DOI:
YANG Yan-min, CHEN Bao-jiu, WANG Cheng, REN Guo-zhong, WANG Xiao-jun, XIA Hai-ping. Spectroscopic Properties of Er<sup>3+</sup> Doped Bi<sub>2</sub>O<sub>3</sub>-B<sub>2</sub>O<sub>3</sub>-SiO<sub>2</sub> Glasses[J]. Chinese Journal of Luminescence, 2006,27(4): 469-473 DOI:
测试了Bi
2
O
3
-B
2
O
3
-SiO
2
玻璃中的Er
3+
离子的吸收光谱、发射光谱、
4
I
13/2
的荧光寿命、拉曼光谱
及OH
-
的傅里叶红外吸收光谱。应用Judd-Ofelt理论计算了该玻璃中的Er
3+
离子的J-O参数、振子强度、
4
I
13/2
能级的寿命
从而利用测得的
4
I
13/2
的荧光寿命得出了
4
I
13/2
能级的量子效率(15%)。由于较低量子效率可能与OH
-
有关
所以计算了玻璃中的OH
-
浓度
发现其浓度较高(1.66×10
19
cm
-1
相当于Er
3+
浓度的3倍)。应用McCumber理论和四能级模型计算了Er
3+
离子的受激发射截面和荧光发射光谱的半峰全宽
结果与通过吸收光谱计算所得基本吻合。根据透射率和折射率的关系计算了折射率
发现和测量值相差很大
说明有较大的散射
通过拉曼光谱和显微镜测试
认为是玻璃中的微小气泡造成的。
Erbium-doped fiber amplifiers(EDFAs) with wide and flat gain spectra in telecommunication windows are the key issues for dense wavelength division multiplexing(DWDM) optical network systems.How-(ever)
the traditional commercialized EDFAs are made of SiO
2
-based material in which Er
3+
ions show a narrow (emission) bandwidth for the
4
I
13/2
→
4
I
15/2
transition.Many methods have been investigated to broaden and flatten the gain spectra of the traditional EDFAs in order to meet the capacity demand.Recently
tellurite glasses have received considerable attention in EDFAs for the broad bandwidth of over 70 nm
which meets the transmission capacity of DWDM systems.Nevertheless
the bad thermal stability and the high up-conversion become the(unsolvable) obstacle.Compared to tellurite
borate is a better glass-former compound and has higher(stability)
larger phonon energy and broad bandwidth.We prepared Er
3+
doped Bi
2
O
3
-B
2
O
3
-SiO
2
glasses according to the following molar composition: 40% Bi
2
O
3
20% B
2
O
3
40% SiO
2
and 3.0% Er
2
O
3
is added to dope the glasses.The absorption spectra for Er
3+
and OH
-
group
emission spectra and luminous decay for the transition
4
I
13/2
→
4
I
15/2
were measured.Accor-(ding) to the standard J-O procedure the intensity parameters for the Er
3+
in the prepared glass were obtained.The concentration of OH
-
group and inner quantum efficiency for
4
I
13/2
level were estimated.It is validated that the lower quantum efficiency is caused by the higher content of OH
-
group
about 3 times of Er
3+
(content.) On the base of McCumber theory
the stimulated emission cross section for the
4
I
13/2
level was derived and found to be in better agreement with the results calculated by using the emission spectra.We draw a conclusion that it is essential for the borate used in EDFAs to decrease the higher content of OH
-
group despite of higher stability
larger phonon energy and broad bandwidth.
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