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暨南大学, 物理系,广东 广州,510632
收稿日期:2005-11-05,
修回日期:2005-12-15,
纸质出版日期:2006-07-20
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吴敬, 仲飞, 刘彭义. 典型有机发光二极管中载流子传输和复合模型[J]. 发光学报, 2006,27(4): 543-546
WU Jing, ZHONG Fei, LIU Peng-yi. The Model of Carriers' Transport and Recombination on the Classical Bilayer OLEDs[J]. Chinese Journal of Luminescence, 2006,27(4): 543-546
提高载流子复合效率是改善有机发光二极管(OLEDs)发光效率的重要方法。采用真空热蒸发成膜法制作了典型双层结构的OLEDs(ITO/TPD/Alq
3
/Al)。二极管的性能测试结果表明器件的电流-电压关系与Fow ler-Nordheim场发射载流子注入理论符合得较好。以Fow ler-Nordheim场发射载流子的隧穿注入理论为基础
对OLEDs的电流进行理论分析和数学推导
建立典型双层结构有机发光二极管中载流子传输、复合的理论模型。以此模型为依据
对载流子注入复合进行理论分析
探究载流子注入复合的效率的表达式。在外加电压和器件材料一定下
得出了载流子复合效率与阳极区一侧积累的空穴面密度和阴极区一侧积累的电子面密度的关系表达式。
OLED(organic light emitting diode) is a very attractive candidate as display devices and for(various) applications.Since Tang
et al
.reported on organic electroluminescence devices
OLED has been widely studied by many researchers and developed as commercial products.Because OLED has a lot of merits from the viewpoint of mobile display such as low power consumption
light weight and thinness
many efforts are(being) made to develop a robust mobile display with OLED.At recent years
in order to improve OLEDs' luminescence-efficiency
much research has been done.However
improving carriers' recombination-efficiency is one of valid approach to improve OLEDs' luminescence-efficiency.Carriers' recombination-efficiency is connect with structures of devices and parameters of materials.So it is necessary to build a model of carriers' transport and recombination for finding out the relation between carriers' recombination-efficiency and the structure or parameters.In this paper
we attempt to build a model of carriers' transport and recombination on the classical bilayer OLEDs.In our experiments
a classical bilayer OLED(ITO/TPD/Alq
3
/Al) is fabricated by thermal evaporation method.We have test the property of the OLED.The result showed that the electricity-voltage relation accords with Fowler-Nordheim tunneling injection theory very well.Basing on Fowler-Nordheim's theory
analyzing the distribution of currents theoretically
and deducing mathematically
a model for carries transport and recombination on the classic OLEDs is presented.According to this model
we analyze carriers' transport and recombination process theoretically and probe into the expression of carriers' recombination-efficiency.Further more
under this model
a formula between the recombination-efficiency and the surface-density of charged carriers
including holes which congregate at the interface on the anode side and the electrons which congregate at the interface on the cathode side
is educed.In this formula
the macroscopic variable (carriers' recombination-efficiency) is expressed by microscopic variables(surface-density of charged car-(riers)).It can offer some theoretical foundation for improving the efficiency of charged carriers recombination in OLEDs from microcoscopic mechanism.
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