LI Guang-po, XU Tie-feng, NIE Qiu-hua, SHEN Xiang. Spectroscopic Properties and Judd-Ofelt Theory Analysis of Er<sup>3+</sup> Doped Tellurite Glass[J]. Chinese Journal of Luminescence, 2006,27(2): 164-168
LI Guang-po, XU Tie-feng, NIE Qiu-hua, SHEN Xiang. Spectroscopic Properties and Judd-Ofelt Theory Analysis of Er<sup>3+</sup> Doped Tellurite Glass[J]. Chinese Journal of Luminescence, 2006,27(2): 164-168DOI:
O-10ZnO) was prepared by the technique of high-temperature melting.The spectral properties
such as absorption spectra and emission spectra of the glass sample have been measured and investigated.The Judd-Ofelt intensity parameters Ω
t
(
t
=2
4
6)(Ω
2
=8.01×10
-20
cm
2
Ω
4
=2.09×10
-20
cm
2
Ω
6
=1.15×10
-20
cm
2
)
transition probabilities
excited state lifetimes and the branching ratios have been predicted of several Er
3+
ions transitions based on the Judd-Ofelt theory.Compared with the other glass hosts
it found that the Ω
2
is bigger of Er
3+
in this tellurite glass
which shows that the covalency between the Er
3+
and O
2-
is stronger than silicate
germanate
fluorid
bismuthate
and phosphate glass.The transition probability of Er
3+
in this tellurite glass is about 492 s
-1
indicating that Er
3+
ions could have strong transition at 1.5 μm in tellurite glass.The broad 1.5 μm fluorescence was observed under 970 nm excitation
and its full width at half maximum(FWHM) is 73 nm.The emission cross-section was calculated according to the McCumber theory.The cross section was quite large due to a large refractive index of the host.The value of FWHM×σ
e
for Er
3+
in tellurite glass is more larger than that of the bismuth
phosphate
germinate and silicate glass.The results showed that the broad and flat
4
I
13/2
→
4
I
15/2
emission of Er
3+
ions around 1.5 μm can be uses as an potential optical amplifier for the wavelength-division-multiplexing(WDM) network system.