WU Hao, PAN Yue-xiao, GUO Chong-feng, ZHANG Xin-min, XU Jian, WANG Yao-hao, YU Bin-hai, LI Xu-feng, SU Qiang. Fabrication and Properties of Rare Earth Phosphors and Their Applications in White-light LEDs[J]. Chinese Journal of Luminescence, 2006,27(2): 201-205
WU Hao, PAN Yue-xiao, GUO Chong-feng, ZHANG Xin-min, XU Jian, WANG Yao-hao, YU Bin-hai, LI Xu-feng, SU Qiang. Fabrication and Properties of Rare Earth Phosphors and Their Applications in White-light LEDs[J]. Chinese Journal of Luminescence, 2006,27(2): 201-205DOI:
Three types of white-light LEDs consisted of "blue LED chip and YAG phosphor"
"blue LED chip
YAG phosphor and red phosphor"
and "blue LED chip
green phosphor and red phosphor" were fabricated.Their CIE parameters were also mearsued under 20 mA DC driving.The CIE coordinates are (0.326
0.339)
(0.326
0.339)
and(0.324
0.324);the correlated color temperature T
c
are 5781
5627
and 5937 K;and the color-rendering index Ra are 82.3
86.2
and 92.2
respectively.It shows that the adding of red light into the white light will improve the quality of the white light.The different DC driving
increasing of the current from 5.0 mA to 6.0 mA
results in higher color temperature T
c
and lower color rendering index.It was found that the red phosphor saturated when the current was higher than 30 mA.The phosphors(
M
1
M
2
)
10
(PO
4
)
6
X
2
(
M
1
=Ca
Sr
Ba;
M
2
=Eu
Mn;
X
=F
Cl
Br) have been synthesized in reductive atmosphere at 900~1200℃ for 2.0~8.0h.The phosphors with different compositions give the emission at 455
477
500
and 580 nm when excited by 400 nm near UV light.Three types of white LEDs were fabricated using UV LED chips and the phosphors mentioned above.The constitutions are "UV LED chip
blue phosphor
and YAG phosphor"
"UV LED chip
blue phosphor and red phosphor"
and "UV LED chip
blue phosphor
green phosphor and red phosphor".Their CIE coordinates are(0.303
(0.329))
(0.327
0.328)
and(0.331
0.333);the correlated color temperature T
c
are 7070
5747
(5566) K;and the color-rendering index Ra are 79.2
80.4
and 87.9 under 20 mA DC driving
respectively.The different DC driving
increasing of the current from 5.0 mA to 6.0 mA result in a higher color temperature T
c
and a lower color rendering index.However
CIE coordinate of the white light LED consisted of UV LED chip