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1. 太原理工大学, 材料科学与工程学院,山西 太原,030024
2. 太原理工大学, 理学院,山西 太原,030024
收稿日期:2004-08-25,
修回日期:2005-03-05,
纸质出版日期:2006-03-20
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王华, 郝玉英, 李洁, 周禾丰, 刘旭光, 许并社. 两种以Znq<sub>2</sub>为基体的新型电致发光材料的合成与性能[J]. 发光学报, 2006,27(2): 249-253
WANG Hua, HAO Yu-ying, LI Jie, ZHOU He-feng, LIU Xu-guang, XU Bing-she. Preparation and Characterization of Two Novel Znq<sub>2</sub>-based Electroluminescent Materials[J]. Chinese Journal of Luminescence, 2006,27(2): 249-253
王华, 郝玉英, 李洁, 周禾丰, 刘旭光, 许并社. 两种以Znq<sub>2</sub>为基体的新型电致发光材料的合成与性能[J]. 发光学报, 2006,27(2): 249-253 DOI:
WANG Hua, HAO Yu-ying, LI Jie, ZHOU He-feng, LIU Xu-guang, XU Bing-she. Preparation and Characterization of Two Novel Znq<sub>2</sub>-based Electroluminescent Materials[J]. Chinese Journal of Luminescence, 2006,27(2): 249-253 DOI:
以8-羟基喹啉为配体的金属配合物是一种性能优良的有机电致发光材料
其中有关8-羟基喹啉铝(Alq
3
)研究已有大量报道
8-羟基喹啉锌(Znq
2
)研究还有待发展。介绍了两种以Znq
2
为基体的新型有机电致发光材料Znq
2
(H
2
O)
2
和(Znq
2
)
4
的合成方法。用IR、XRD、TG、DTA和荧光测试方法进行表征与分析表明:Znq
2
(H
2
O)
2
和(Znq
2
)
4
的玻璃化温度(
T
g
)分别为104.2℃和204.9℃;在161℃下Znq
2
(H
2
O)
2
脱去水分子成为Znq
2
在361℃高温下四聚体(Znq
2
)
4
裂解为单体Znq
2
;Znq
2
(H
2
O)
2
和(Znq
2
)
4
具有很好的发光性能
在光致发光谱中λ
max
分别是505
550nm。
Since Tang
et al
.developed a very high efficient fluorescent material(Alq
3
) and made the first OELD in 1987
novel organic electroluminescent materials had attracted much interest.Though developed for ten years more
the performances of 8-hydroxyquinoline metal complexes were more excellent than other organic electroluminescent materials in commerce utilizations
such as good light performance
good thermal stability
and good film formability.Alq
3
was the best representation
research on performances and applications of Alq
3
has matured.But the research on Znq
2
was not enough
which limited the commerce utilizations as an excellent organic electroluminescent material.At this point
some foundation research works were done here.Two Znq
2
-based organic electroluminescent materials
Znq
2
(H
2
O)
2
and(Znq
2
)
4
were prepared and characterized by infrared absorption spectrum(IR)
X-ray diffraction(XRD)
thermogravimetry(TG)
differential thermal analysis(DTA)
photoluminescence(PL) spectrum and electroluminescence(EL) spectrum.It was shown that the deviating temperature of H
2
O from Znq
2
(H
2
O)
2
is 161℃
the decomposing temperature of(Znq
2
)
4
into Znq
2
is 361℃
the glass transition temperature of Znq
2
(H
2
O)
2
is 104.2℃ and that of(Znq
2
)
4
is 204.9℃.In PL spectra
the peak wavelengths of Znq
2
(H
2
O)
2
and(Znq
2
)
4
are 505 nm and 550 nm respectively.In EL spectra
the peak wavelength of (Znq
2
)
4
is 539 nm.Because of special molecular spatial structure of(Znq
2
)
4
there is an electron tunnel between adjacent(Znq
2
)
4
molecules
which could increase electron transition efficiency from HOMO to LUMO and decrease drive voltage of OELD.The high glass transition temperature of(Znq
2
)
4
could prolong the lifetime of OELD. Above all
(Znq
2
)
4
have great potential in use as organic electroluminescent material.In addition
(Znq
2
(H
2
O)
2
) has great light intensity and narrow FWHM in PL spectra
and it is also a kind of potential(excellent) organic electroluminescent material.Application of(Znq
2
)
4
and Znq
2
(H
2
O)
2
in OELD will be discussed in detail in future articles.
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