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1. 浙江大学, 材料科学与工程系,浙江 杭州,310027
2. 浙江大学, 硅材料国家重点实验室,浙江 杭州,310027
收稿:2004-08-25,
修回:2005-4-5,
纸质出版:2006-03-20
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张朋越, 向鑫, 沈华翔, 潘毓, 洪樟连, 王民权. Li<sub>2</sub>CO<sub>3</sub>/K<sub>3</sub>PO<sub>4</sub>复合助熔剂对新型Y<sub>2</sub>O<sub>2</sub>S:0.09Ti长余辉磷光体发光性能的影响[J]. 发光学报, 2006,27(2): 169-173
ZHANG Peng-yue, XIANG Xin, SHEN Hua-xiang, PAN Yu, HONG Zhang-lian, WANG Min-quan. Influence of Li<sub>2</sub>CO<sub>3</sub>/K<sub>3</sub>PO<sub>4</sub> Flux Ratio on the Luminescent Properties of Y<sub>2</sub>O<sub>2</sub>S:Ti Phosphor[J]. Chinese Journal of Luminescence, 2006,27(2): 169-173
张朋越, 向鑫, 沈华翔, 潘毓, 洪樟连, 王民权. Li<sub>2</sub>CO<sub>3</sub>/K<sub>3</sub>PO<sub>4</sub>复合助熔剂对新型Y<sub>2</sub>O<sub>2</sub>S:0.09Ti长余辉磷光体发光性能的影响[J]. 发光学报, 2006,27(2): 169-173 DOI:
ZHANG Peng-yue, XIANG Xin, SHEN Hua-xiang, PAN Yu, HONG Zhang-lian, WANG Min-quan. Influence of Li<sub>2</sub>CO<sub>3</sub>/K<sub>3</sub>PO<sub>4</sub> Flux Ratio on the Luminescent Properties of Y<sub>2</sub>O<sub>2</sub>S:Ti Phosphor[J]. Chinese Journal of Luminescence, 2006,27(2): 169-173 DOI:
采用高温还原法合成了一种新型无稀土掺杂Y
2
O
2
S:0.09Ti长余辉发光材料。基于助熔剂种类对长余辉发光材料特性的重要作用
选择了对余辉衰减初期和后期余辉强度有明显作用的Li
2
CO
3
和K
3
PO
4
两种助熔剂
研究了不同配比(以下用
x
表示
x
=Li
2
CO
3
/(Li
2
CO
3
+K
3
PO
4
))的复合助熔剂对Y
2
O
2
S:0.09Ti磷光体晶体结构和发光性能的作用
以获得具有较好综合发光性能的Y
2
O
2
S:0.09Ti磷光体。采用PL光谱和余辉测试仪对材料的发光特性进行了表征
用XRD研究了其晶体结构的变化。XRD结果表明
在复合助熔剂范围内(
x
=0~1.0)均可获得单相性的Y
2
O
2
S:0.09Ti磷光体。同时发现复合助熔剂比例不同制备的样品中
Y
2
O
2
S:0.09Ti磷光体晶体择优取向也发生明显的变化
且高比例Li
2
CO
3
有助于Y
2
O
2
S:0.09Ti磷光体的晶体形成。复合助熔剂比例
x
对样品的激发峰与发射谱主峰位置(565nm)基本没有影响;但助熔剂比例
x
对发射峰强度则有明显影响
随着
x
增加
该磷光体的发光强度先增后减
在
x
=0.8时发光强度最大。
As the added flux has much more severe effect on the luminescence properties
the influence of Li
2
CO
3
/(Li
2
CO
3
+K
3
PO
4
) flux ratio
x
(
x
= Li
2
CO
3
/(Li
2
CO
3
+K
3
PO
4
)) on the luminescence properties of Y
2
O
2
S:0.09Ti phosphor has been investigated to obtain the best luminescence and afterglow intensity.The composite flux of Li
2
CO
3
plus K
3
PO
4
was selected because Li
2
CO
3
and K
3
PO
4
flux have been demonstrated in previous study to improve the afterglow intensity in the beginning stage and long time stage
respectively.PL spectra and afterglow measurement were used to analyze the effect of flux ratio on the luminescence and after glow properties of Y
2
O
2
S:0.09Ti phosphor.And XRD measurements were carried out to verify the crystal structure.XRD results showed that the single phase Y
2
O
2
S:0.09Ti phosphor could be obtained when flux ratio x increases from 0 to 1.0
while the grain growth orientation may change obviously.The fact that excitation spectra are similar in all flux range demonstrates that the flux ratio has little effect on the excitation process.Nevertheless
the emission spectra showed that the intensity of emission peak at 565 nm depended greatly on the flux ratio.Luminescence intensity of Y
2
O
2
S:Ti phosphor increased with an increase of Li
2
CO
3
ratio x
then reduced as x over 0.8.On the other hand
afterglow brightness of Y
2
O
2
S:Ti was enhanced at appreciate Li
2
CO
3
/(Li
2
CO
3
+K
3
PO
4
) ratio of about 0.4 with an enhanced afterglow brightness(9.1 mcdm
-2
) at(decay) time of 30 min.This value is about four times as that of single Li
2
CO
3
doping(2.4 mcdm
-2
)
and two times as that of single K
3
PO
4
doping(4.3 mcdm
-2
).Above results about the effect of flux ratio on luminescence after glow properties could be used to adjust the overall properties of Y
2
O
2
S:0.09Ti phosphor.The best afterglow with yellow color is obtained at appreciate Li
2
CO
3
/(Li
2
CO
3
+K
3
PO
4
) ratio of about 0.4
and its afterglow can last over 5 h with recognizable intensity level(0.32 mcd/m
2
) after the removal of the excitation light.
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