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昆明物理研究所, 云南昆明 650223
收稿日期:2004-08-25,
修回日期:2004-12-26,
纸质出版日期:2005-11-20
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黄晖, 潘顺臣, 姬荣斌, 杨文运, 赵增林. 射线探测用碲锌镉晶体及其器件研究[J]. 发光学报, 2005,26(6): 807-812
HUANG Hui, PAN Shun-chen, JI Rong-bin, YANG Wen-yun, ZHAO Zeng-lin. Research on the Cadmium Zinc Telluride Crystal and Its Device for Radiative Ray Detection[J]. Chinese Journal of Luminescence, 2005,26(6): 807-812
采用改进的布里奇曼(Bridgman)方法进行锌组分为0.15碲锌镉(Cd
0.85
Zn
0.15
Te)晶体的生长.通过严格控制晶体生长过程中Cd的蒸气分压
使得所生长的碲锌镉晶体在结晶质量方面达到了较好的水平.对其性能进行测试
红外透射比
T
>
60%、沉积相密度
<
1×10
4
/cm
2
、位错腐蚀坑密度DEPD
<
6×10
4
/cm
2
、X射线衍射双晶回摆曲线半峰全宽FWHM
<
20arcsec、电阻率ρ
>
10
4
Ω·cm.利用所生长的晶体初步制作了平面型单元碲锌镉射线探测器
所用晶体的尺寸为5mm×5mm×2.5mm
制成的探测器在室温下对
125
I和
241
Am放射源进行了探测测量.对125I放射源
探测出了强度为74.5%的27.5keV的γ射线特征峰
不能仔细分辨出强度为39.8%的27.2keV的γ射线特征结构;对
241
Am放射源
探测出了59.5keV的γ射线特征峰
分辨率优于6keV
半峰全宽FWHM
<
10%
同时还能检测出Te、Cd的X射线逃逸的混合峰以及241Am低能Te-K系、Np-L系的两个X射线特征峰.
Cadmium zinc telluride(Cd
1-y
Zn
y
Te
CZT) is the first choice of material for room temperature X-ray and gamma-ray detectors.The common growth techniques are the conventional vertical Bridgman and the high pressure Bridgman method.CZT's large average atomic number
Z~50
makes photoelectric absorption the dominant interaction below 250 keV
and its high density
5.8 g/cm
3
results in short interaction lengths.CZT's large band gap also results in low leakage current and low noise at room temperature.In this research work
the improved vertical Bridgman crystal growth method is used to grow CZT crystal with a nominal Zn concentration of 15 atomic percent
namely Cd
0.85
Zn
0.15
Te.Through by strictly controlling of the cadmium vapor pressure
the high quality CZTingots were obtained.The characterization by several method of CZT(wafer) resulted in
FTIR transmittance
T
>
60% within spectra range 2.5~20 μm at room temperature
the density of precipitate
<
1×10
4
/cm
2
with the precipitate diameter ≤15 μm
dislocation etch pit density DEPD
<
6×10
4
/cm
2
full width at half-maximum of X-ray rocking curve values FWHM
<
20 arcsec with the Cu Kα1 radiation and Si three-crystal monochromator and 15 mm×15 mm spot size
the electrical resistivity ρ
>
10
10
Ω·cm.The single element planar detector for radiative ray detection fabricated with CZT crystal mentioned above is performed.The size of CZT crystal for detector is 5 mm×5 mm×2.5 mm.On both sides of 5 mm×5 mm surface
gold and gold/platinum were evaporated as electrodes.The energy spectra to standard radiation source
125
I and
241
Am were performed by CZT planar detector.The applied bias voltage for CZTplanar detector is 200 V.The characteristic γ-radiation peak of
125
I at 27.5 keV with intensity 74.5% is detected and the characteristic γ-radiation peak of
125
I at 27.2 keV with intensity 39.8% can not be recognized from the energy spectrum for
125
I.The characteristic γ-radiation peak of
241
Am at 59.5 keVis measured with the full width at half-maximum FWHM
<
10%
viz.the resolution is better than
6
keV.In the mean time
the characteristic X-ray escape mixing peaks of tellurium and cadmium located at 34 keV is detected and two characteristic X-radiation peaks of Te-K
α
1
α
2
at 27 keV and Np-L
β1
at 17.5 keV are also recognized.
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