CHEN Zhi-jian, LI Fu-shan, GONG Qi-huang. Novel Blue Organic Light-emitting Diodes and Materials[J]. Chinese Journal of Luminescence, 2005,26(6): 743-747
CHEN Zhi-jian, LI Fu-shan, GONG Qi-huang. Novel Blue Organic Light-emitting Diodes and Materials[J]. Chinese Journal of Luminescence, 2005,26(6): 743-747DOI:
The organic light-emitting diodes have been considered for applications in backlights of liquid-crystal displays
ultrathin plat full-color display
efficient illuminators and electro-pumped organic solid laser
etc.The process responsible for electroluminescence requires the injection of electrons from one electrode and holes from the other
the electron-hole pairs form excitons in emitting layer
and then the light generate through the radiative recombination of the excitons.In the past near upon twenty years
great progress has been made in electroluminescent devices and materials.Up to now
the three primary colors of red
green and blue
which are required for full-color displays
have been achieved.Among these
the green emission is the most perfect and the corresponding device almost reaches to commercial criterion.However
the blue and red emissions are more challenging
and there are many activities to be focused on efficient blue and red light-emitting materials.This paper reviews our recent works on blue organic light-emitting diodes
including blue materials
such as the metal chelate complex
(2
3-methyl-8-hydroxy-quinoline) lithium(LiMMq)
and derivates of polyfluorene
dendritic polyfluorene(PDFA)
and blue electroluminescent devices based on exciplex emission formed at the interface between9
9-Dibutyl-N
N
N'
N'-tetraphenyl-9H-fluorene-2
7-diamine(DTFD) and 2
2-[1
2-phenylenebis(oxy)] bis(N
N'-diphenyl-acetamide)(PBD).The performances of the blue emitting materials and the devices have been studied by photoluminescent
electroluminrescent spectra and characteristic of current-brightness-bias voltage etc.The life-time and color-purity of blue organic light-emitting diodes are required to be further improved for the commercial production.