ZHANG Jian, WANG Shi-wei, AN Li-qiong, LIU Min, CHEN Li-dong. Upconversion Luminescence in Yb<sup>3+</sup>,Er<sup>3+</sup>:Y<sub>2</sub>O<sub>3</sub> Nanocrystalline Powders Excited by a<sub>980</sub> nm Laser Diode[J]. Chinese Journal of Luminescence, 2005,26(6): 789-793
ZHANG Jian, WANG Shi-wei, AN Li-qiong, LIU Min, CHEN Li-dong. Upconversion Luminescence in Yb<sup>3+</sup>,Er<sup>3+</sup>:Y<sub>2</sub>O<sub>3</sub> Nanocrystalline Powders Excited by a<sub>980</sub> nm Laser Diode[J]. Chinese Journal of Luminescence, 2005,26(6): 789-793DOI:
thermal stability and a relatively low phonon energy(430~550 cm
-1
).These aspects make Y
2
O
3
a promising host for upconversion applications.Y
1.98
Yb
0.01
Er
0.01
O
3
nanocrystalline powders were prepared via a co-precipitation method using nitrates
ammonia and ammonium hydrogen carbonate as raw materials.The X-ray diffraction results showed that the as-prepared powders were cubic phase of Y
2
O
3
after fired at 700℃ for 2 h.Field emission scanning electronic microscopy revealed that most of the particles were nearly spherical and the average diameter of the particles was in the range of 60~80 nm.The upconversion spectroscopic properties of the powders were investigated under the excitation of a 980 nm continuous wave diode laser.Strong red and green upconversion emissions which centered at 660 nm and 562 nm respectively were observed.The red emission was assigned to the transitions of
4
F
9/2
→
4
I
15/2
energy levels of Er
3+
ions
while the green emission was attributed to the transitions of
2
H
11/2
/
4
S
3/2
→
4
I
15/2
energy levels of Er
3+
ions.The dependence of the intensity of upconversion emissions upon the excitation power of the diode laser suggested that two-photon absorption processes are involved in the green and red upconversion luminescence.The excited state absorption of Er
3+
ions and the energy transfer from Yb
3+
to Er
3+
ions are main upconversion mechanisms.Due to its highly efficient upcovnersion luminescence
this material could find applications in the fields of fluorescent labels and infrared detection.