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1. 中国科学院, 研究生院 北京,100049
2. 中国科学院长春光学精密机械与物理研究所, 激发态物理重点实验室,吉林 长春,130033
3. 西安近代化学研究所,陕西 西安,710065
收稿日期:2005-08-09,
修回日期:2005-08-13,
纸质出版日期:2005-09-20
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徐茂梁, 李文连, 李天乐, 安忠维, 柴生勇, 周群. 一种新型铱(Ⅲ)配合物及其有机电致发光器件[J]. 发光学报, 2005,26(5): 690-692
XU Mao-liang, LI Wen-lian, LI Tian-le, AN Zhong-wei, CHAI Sheng-yong, ZHOU Qun. A New Iridium(Ⅲ) Complex and Its Application in Organic Electrophosphorescent Device[J]. Chinese Journal of Luminescence, 2005,26(5): 690-692
徐茂梁, 李文连, 李天乐, 安忠维, 柴生勇, 周群. 一种新型铱(Ⅲ)配合物及其有机电致发光器件[J]. 发光学报, 2005,26(5): 690-692 DOI:
XU Mao-liang, LI Wen-lian, LI Tian-le, AN Zhong-wei, CHAI Sheng-yong, ZHOU Qun. A New Iridium(Ⅲ) Complex and Its Application in Organic Electrophosphorescent Device[J]. Chinese Journal of Luminescence, 2005,26(5): 690-692 DOI:
报道了一种新的基于2
5-二(4-乙基苯基)吡啶配体的铱(Ⅲ)配合物
并用于有机电致发光器件
得到λ
max
=548nm的绿光发射
其最大发光效率为23cd/A
最大亮度为10800cd/m
2
。与基于其他绿光铱(Ⅲ)配合物的器件相比
该器件的电流饱和特性也得到进一步改善。
Organic light-emitting devices(OLEDs)
which consist of organic thin films and exhibit light emission under electric current excitation
are expected to be one of the most promising candidates for flat panel display.After Tang reported the efficient double-layer OLEDs
different types of fluorescent materials have been studied and tremendous progress has been made in the past decade.To further improve EL efficiency
the organic phosphorescent materials
which harvest excitation energy of both singlet and triplet states
have been introduced in OLEDs.By employing the phosphorescent materials
the internal quantum efficiency can theoretically reach 100% and emission color can be tuned by modifying the phenylpyridine ligand.The complexes based on Ir(ppy)
3
skeleton have such a simple molecular structure and excellent luminescent properties that many efforts are still focusing on chemical modification of this type of complexes for better electrophosphorescent performance.We synthesized a new iridium(Ⅲ) complex
iridium(Ⅲ) bis(2
5-di(4-ethylphenyl)pyridinato-N
C2′)acetylacetonate [(deppy)
2
Ir(acac)]
based on
2
5-di(4-ethylphenyl)pyridine ligand.ELdevice was fabricated based on
6
%(mass fraction) of(deppy)
2
Ir(acac) doped in CBP.Amaximum luminance efficiency of 23 cd/A and a peak luminance of 10800 cd/m
2
were achieved
the device showed green emission corresponding to a maximum wavelength of 548 nm.On the other hand our electrophosphorescent devices show excellent current saturation behavior at higher current density.
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