YANG Zhi-ping, LIU Chong, GUO Zhi, FENG Jian-wei, YANG Yong, LI Xing-min, LI Xu. Preparation of CaTiO<sub>3</sub>:Pr<sup>3+</sup> Red Long Afterglow Glass and Their Luminescent Properties[J]. Chinese Journal of Luminescence, 2005,26(4): 493-496
YANG Zhi-ping, LIU Chong, GUO Zhi, FENG Jian-wei, YANG Yong, LI Xing-min, LI Xu. Preparation of CaTiO<sub>3</sub>:Pr<sup>3+</sup> Red Long Afterglow Glass and Their Luminescent Properties[J]. Chinese Journal of Luminescence, 2005,26(4): 493-496DOI:
The green and blue long-lasting luminescent glass has been successfully prepared
but the red long-lasting luminescent glass has not been reported at the present time. CaTiO
3
:Pr
3+
red long-lasting luminescent glass was obtained by two steps method. At the first
CaTiO
3
:Pr
3+
long lasting luminescence powder and low melting glass powder were synthesized by high-temperature solid-state reaction respectively. Secondly
the two components were weighed in appropriate mass ratio and mixed homogeneously. Finally
the mixtures obtained were sintered at different temperature for 10 min. The afterglow properties were researched systemically. The effects of the amount of CaTiO
3
:Pr
3+
in mixtures and the procedure conditions were studied also.The emission spectra of samples were measured. The emission peaks at 611.7 nm and 614.5 nm
corresponding to the transition 4f-4f(
1
D
2
3
H
4
)of Pr
3+
ions
come from the CaTiO
3
:Pr
3+
red long (afterglow) emission. There was a broad band from 350 nm to 550 nm in the excitation spectrum
which showed that the glass could absorb the energy from near ultraviolet to yellow green
so the samples could be excited by sun light and lamplight then emitte the red long lasting afterglow. When the mass proportion of glass powder and phosphors is within 95:5~80:20
the pure glass phase could be gained and excellent red long afterglow could be observed. The effects of the atmosphere and the fuse temperature on the luminescent property were studied. The samples prepared at 800℃ in air have better (luminescent) characteristic.